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Archive for the ‘Flame Retardants’ Category

You all are being conned into diverting your attention away from the greatest threat to life. The greatest threat to our planet is the building of this ruling class capitalist munitions branch.
 
So many fixate on the Pentagon and political puppets but few examine the powerful capitalists who control it. They’ve been consolidating their power, if you have not noticed. Few bother studying them and the markets they profit from by robbing the working class blind and destroying them every step of the way. As long as the working class ignore who is truly running this nation and expose their crimes, nothing will ever change.
 
“DuPont chemical company, which until recently operated a site in Parkersburg that is more than 35 times the size of the Pentagon” – The Lawyer Who Became DuPont’s Worst Nightmare
 
Dow Chemical and DuPont Have Completed a $130 Billion Merger.
 
“Nuclear weapons contractors repeatedly stifle whistleblowers, auditors say. The Energy Department lets its private contractors police themselves, producing “chilled work environments” in which employees who find wrongdoing have no useful path for complaints”
 
Dow Chemical and General Electric have yet been held financially accountable for damages to communities or cleaned up the superfund sites they created from the last arms race. Dow Chemical and General Electric are two of those concealed institutions that our government serves with clearly no oversight and none on the horizon.
 
 
And since our Trillion dollar weapons upgrade is being created under these current conditions, I’m sure this time we are far more likely to nuke ourselves in the process of this “upgrade.”
 
“Drawing on recently declassified documents and interviews with people who designed and routinely handled nuclear weapons, Command and Control takes readers into a terrifying but fascinating world that, until now, has been largely hidden from view. Through the details of a single accident, Schlosser illustrates how an unlikely event can become unavoidable, how small risks can have terrible consequences, and how the most brilliant minds in the nation can only provide us with an illusion of control. Audacious, gripping, and unforgettable, Command and Control is a tour de force of investigative journalism, an eye-opening look at the dangers of America’s nuclear age.”
 
When will we ever learn that putting power in the hands of those only interested in greed will destroy us all and think nothing of it.
 
 
Why?
 
“The United States must remain at the frontier of nuclear technology, even while it negotiates about restraint in its use. From the perspective of the past century’s absence of a major power conflict, it could be argued that nuclear weapons have made the world less prone to war.” – World Order by Kissinger (page 340 – 341.) & Hillary agreed because Kissinger is the policy voice of the Deep State. “Henry Kissinger’s book makes a compelling case for why we have to do it and how we can succeed.” – Hillary Clinton.
 
American psychos….
 
The United States is currently appropriating $1 Trillion dollars over the next 30 years to upgrade our nuclear weapons program because that’s apparently a high priority for us here in the states…. or should I say Dow Chemical, DuPont, General Electric, and company need a huge subsidy infusion of billions of dollars. I wonder why? Could it possibly be because some of their current investments are in trouble because consumers realize their products are actually destroying them?
 
 
The other 9/11 you’ve never heard about…
 
“Department of Energy officials deny this, but it’s likely that a criticality — a nuclear chain reaction — occurred during the 1957 fire…. Elements such as strontium-90 and cesium-135 never occur except in the case of a nuclear chain reaction. Based on soil and water testing completed decades later that detected the presence of these elements, some experts — despite the government’s insistence that there has never been a criticality at Rocky Flats — believe that a criticality accident producing various fission products may have occurred on September 11, 1957.
 
But the worst thing about the fire was that no one — except for officials with the Department of Energy and Rocky Flats (then operated by Dow Chemical) — knew about it. There was no public evacuation, no warning, nothing in the press. Local citizens had no idea. This fire was deliberately hidden from public view. People were exposed to plutonium and other contaminants without their knowledge, although officials at the plant were aware of what was going on.
 
COHEN: How long did it take for the government, and the private entities involved, to admit to what happened on September 11, 1957? When did it dawn on people, in the area and elsewhere, that this great event had occurred?
 
IVERSEN: Thirteen years passed before the public began to learn that this fire occurred and had contaminated the Denver metro area — and it took another devastating fire to force the government and the private companies that operated Rocky Flats to reveal the truth….
 
“For some, the story of Rocky Flats, one of the most disgraceful episodes in the annals of America’s interaction with the atom, is ancient history. For others, it’s a current event. For Kristen Iversen, it’s a burden she lives with, physically and psychologically, every day of her life. Iversen is the author of a new book on the subject — Full Body Burden: Growing Up in the Nuclear Shadow of Rocky Flats, a striking tale of innocence in a time and a place of great danger. It’s the story of an American family buying into the myth of nuclear safety, a story of an abuse of trust for which our government still hasn’t fully atoned.”
 
Nuclear Energy feeds into all fluoride-based capitalist markets.
 
The Fluoride Deception: How a Nuclear Waste Byproduct Made Its Way Into the Nation’s Drinking Water – A new book, titled “The Fluoride Deception” by Christopher Bryson examines the background of the fluoridation debate. According to Bryson, research challenging fluoride’s safety was either suppressed or not conducted in the first place. He says fluoridation is a triumph not of medical science but of US government spin.
 
* Christopher Bryson, has reported science news stories for many media outlets including the BBC, Christian Science Monitor and the Discovery Channel. He was part of an investigative team at Public Television that won a George Polk Award for “The Kwitny Report.”
 
“Sodium fluoride is used as a rat poison for a long time.”
…In essence, the uranium and fluoride that was necessary for enriching of the uranium and produced this by-product and obviously this waste of fluoride in my mind it sounds very similar to the issue of depleted uranium , again, being a by-product of the nuclear industry and the need then to sanitize these waste products from our nuclear industry, for the public to get rid of them in other words , right? So, it’s—could you talk a little bit about the role of Edward Bernays, ,the father of propaganda or public relations in America in convincing the public about this?
 
CHRISTOPHER BRYSON: Yes, the Manhattan Project with the World War II, very secret project to make the atomic bomb. I went to industry archives, a very large, significant industry archive out at the University of Cincinnati and found that the very same health researcher , Dr. Robert Kehoe who headed up the laboratory at the University Of Cincinnati, he spent his entire career telling the United States’ public health community that adding lead to gasoline was safe. That’s now being discredited. He was also one of two leading public health scientists saying that adding fluoride to water was safe and good for children. So, that’s the—some of the material that this book gets into.”
 
 
Perfluorinated Compounds (PFCS) The Devil We Know
Chasing Molecules excerpt explaining the ethylene tree branch of perfluorinated compounds. It’s our whole economic model that needs to be re-designed. Munition technologies have evolved significantly.
 
(Always remember that DuPont’s nickname was “The Merchants of Death” in the early 1900s for a reason)
 
Chapter 7: Out of the Frying Pan
Excerpt on Perfluorinated compounds (PFCs)
 
“This scenario of new materials with comparable intrinsic hazards being offered as alternatives to restricted products is now being repeated with perfluorinated compounds (PFCs). This is a family of compounds from an alphabet soup of names that are used to create non-stick, stain-repellant, and waterproof surfaces and films for both industrial and consumer applications—compounds so widely used that the EPA describes human exposure to these chemicals as “ubiquitous.” Perfluorinated compounds also provide an illustration of how difficult it is under our current chemical regulatory system to find out what is in a commercially marketed synthetic chemical even when it’s being used in contact with food or in products that touch our bodies. They also clearly demonstrate why it’s so important to ask questions about new materials’ biochemical behavior, molecular structure, and behavior—and not simply about performance and expedient production—as they’re being designed for a pharmaceutical or a frying pan.
 
Among this class of synthetic chemicals that we’ve been wrapping around food, sitting on, and wearing are substances that have been linked to impaired liver and thyroid function, immune and reproductive system problems, altered production of genetic proteins involved in cellular development, to tumor production in lab animals, and to elevated cholesterol levels in children, as well as to changes in metabolism, including how the body processes fat. These compounds are endocrine-disrupting properties and have been linked to cancer.
 
These perfluorinated chemicals—also sometimes referred to as perfluorocarboxylates (PFCAs) or fluoropolymers—are physically long chain molecules, made up predominantly of carbons and fluorines, in which the carbons are surrounded by fluorine atoms. (In chemistry, the prefix “per” describes a molecule that has the maximum amount of a particular element for its configuration. In the case of PFCs, each molecule has as many fluorine atoms attached as that structure can support.) Their varying lengths and structures depend on how, by whom, and for what purpose they are manufactured. This combination of elements makes strong, flexible, liquid-resistant, and slick-surfaced polymers. They are used as photoresist compounds in semiconductor manufacture, as fire-fighting foams, as insulation in plastics that sheathe wires and cables, as grease-resistant coating on pizza boxes, takeout food containers, microwave popcorn bags, and other packaging, including the support cards in candy and bakery items. They’re also used to make carpets, upholstery, and clothing fabrics (including leather) stain- and water-resistant—and are even added to toilet cleaner.
 
Among these compounds is one known as perfluorooctane sulfonate (FPOS). PFOA—made with eight carbon atoms and sometimes referred to as C8—is an ingredient of yet another per fluorinated compound called polytetrafluoroethylene (PFTE) that made up the original formulation of the products sold under the names Teflon, Gore-Tex, and Scotchguard. The structure that makes PFOA, PFOS, and PFTE so strong and durable also means that they resist degradation in the environment. They do so to such an extent that, like other persistent pollutants, they are chemical globetrotters. They are being found in Arctic animals, both fish and mammals—including polar bears—as well as in ice and snow. They’ve been found in Lake Ontario trout, in bird eggs collected along the Baltic Sea, in plant tissue, in mink liver, and in threatened and endangered sea turtles along the southern coast of the United States, including the Kemp’s Ridley sea turtle, now the scarcest of loggerhead sea turtles. Levels of PFOA and PFOS measured in sea otters along California coast reported in 2006 were the highest yet found in sea mammals.
 
While these fluoropolymers and the smaller molecules into which they break down are being found in remote locations and far from where their products were used or made, they are also being detected in human bio monitoring studies all around the world. Testing by the 3M Company—until 2000, itself a major PFOA producer—found PFCs in 95 precent of the Americans it surveyed, while researchers from the Center for Disease Control found such compounds in 98 percent of the Americans it tested. These compounds have even been found in fetal cord blood of newborn babies. These babies, part of a study conducted in Baltimore, Maryland, were also predominately low-birth-weight babies, suggesting that there may be a connection between PFC exposure and prenatal development. Subsequent studies found similar incidence of low birth weights in babies born to mothers in Denmark carrying PFOA in their blood. As has been observed in some PBDE studies, PFC levels in children taken from biomonitoring studies appeared to be higher that those in adults in the same studies. Given that PFOA can last years and that reexposure is almost certain under current conditions, it’s not surprising that children have been found to carry proportionally higher loads of these chemicals than do adults.
 
There are so many of these compounds at large in the environment and PFCs last so long that PFOA has now been detected in deep ocean environments in the Labrador Sea, which occupies a critical location in global ocean circulation and could send contaminants into either European or North American Arctic, thus extending their routes of potential exposure to people and wildlife. Factor in subsistence global warming in the far north and it’s likely these contaminants’ potential impacts will be felt more directly than in more southerly locations….
 
In late 2008, PFOA and PFOS were found in sewage sludge used as fertilizer on agricultural fields used for cattle grazing near Decatur, Alabama, where there was fear that the meat itself might be contaminated. The chemicals are thought to have originated in wastewater from nearby chemical manufacturing plants. Similar cases of PFC contamination of waterways and sludge have been reported across the United States and elsewhere around the world.
 
Meanwhile, workers at plants that produce PFCs have routinely been testing positive for these compounds. Such discoveries date back to 1978. Testing of DuPont workers done throughout the 1980s and the 1990s found elevated blood levels of PFOA and employees at DuPont’s West Virginia plant were found—in company studies—also to have higher than normal rates of leukemia, heart problems, atherosclerosis, and aneurysms. Women at a 3M plant who’d worked with these chemicals reported instances of birth defects in their children in the early 1980s, and in 1997 traces of PFOA and PFOS were reported in donated blood supplies…
 
There turn out to be a number of nonstick cookware lines now being sold under the banner of “PFOA-free.”…. There are a number of these PTFE-based “PFOA-free” products now being made by DuPont and other PFC manufacturers.
 
How, I wondered, could a material be “PFOA-free” yet made with polytetrafluoroethylene (PTFR)? For an explanation, I spoke to Olga Nadeinko, a senior scientist with the Environmental Working Group. These compounds are big, Christmas tree-like polymers, she says, explaining that “the carbon backbone of the molecule is the trunk of the tree and the side chains with the fluorine atoms are the branches.” PFOA is also known as C8 because it has eight carbon atoms from which its fluorine branches stem. One of the new perfluorinated compounds being used as an alternative to PFOA or C8, she explains is a compound known as perfluorohexanoic acid (PFHxA)—or C6, so named for the six carbon atoms in the molecules that make up the backbone or tree trunk of this PFC.
 
“What happens,” Nadeinko continued, “is that eventually the branches break off the tree” and these branches that form six-, seven-, and eight-carbon-chain molecules are among the perfluorinated compounds now being found in children and adults. “In the human body, PFOA can last two to fourteen years—on average five—and honestly, you don’t want it there,” says Nadeinko. And these fluorine branches, she points out, can break off PFC trees with six carbons in their initial formulation just as they can from those with eight carbons.
 
Yet DuPont, one of the several companies offering products based on C6 chemistry, states that these Capstone products “are based on short chain molecules that cannot break down to PFOA in the environment.” The technology used to produce this new product, we’re told, requires “negligible PFOA and PFOA precursor content.” While the company maintains that these products are not made with PFOA, it also says that it “believes that no one can substantiate statements that fluorotelomer products [the basis of chemistry] are ‘PFOA Free’ or have ‘Zero PFOA’ even if test results are below the limit of detection.” This circular statement would seem to indicate that while these products are being marketed as “PFOA-free,” they actually may contain—and therefore be made with—these compounds….
 
Toxic effects observed have resulted not only from C8 but also from exposure to C6, and it appears that very small amounts—in micro molar concentrations—can produce adverse effects… Scientists can now locate the precise genetic receptors where many such chemical interactions occur and have learned that certain synthetic chemicals have molecular compositions and structures that enable them to interact with the site where a hormone would bind. This has been discovered for a number of common synthetic chemicals, including bisphenol A and the other chemicals Bruce Blumberg of UC Irvine called “obesogens,” for dioxins, and for perfluorinated compounds.” – Chasing Molecules: Poisonous Products, Human Health, and the Promise of Green Chemistry by Elizabeth Grossman
 
The Lawyer Who Became DuPont’s Worst Nightmare..
 
“At one point, the video cuts to a skinny red cow standing in hay. Patches of its hair are missing, and its back is humped — a result, Wilbur speculates, of a kidney malfunction. Another blast of static is followed by a close-up of a dead black calf lying in the snow, its eye a brilliant, chemical blue. ‘‘One hundred fifty-three of these animals I’ve lost on this farm,’’ Wilbur says later in the video. ‘‘Every veterinarian that I’ve called in Parkersburg, they will not return my phone calls or they don’t want to get involved. Since they don’t want to get involved, I’ll have to dissect this thing myself. … I’m going to start at this head.’’
 
The video cuts to a calf’s bisected head. Close-ups follow of the calf’s blackened teeth (‘‘They say that’s due to high concentrations of fluoride in the water that they drink’’), its liver, heart, stomachs, kidneys and gall bladder. Each organ is sliced open, and Wilbur points out unusual discolorations — some dark, some green — and textures. ‘‘I don’t even like the looks of them,’’ he says. ‘‘It don’t look like anything I’ve been into before.’’
 
Bilott watched the video and looked at photographs for several hours. He saw cows with stringy tails, malformed hooves, giant lesions protruding from their hides and red, receded eyes; cows suffering constant diarrhea, slobbering white slime the consistency of toothpaste, staggering bowlegged like drunks. Tennant always zoomed in on his cows’ eyes. ‘‘This cow’s done a lot of suffering,’’ he would say, as a blinking eye filled the screen.
 
‘‘This is bad,’’ Bilott said to himself. ‘‘There’s something really bad going on here.’’
 
 
And since ABC removed this story regarding DuPont’s PFOAs
 
Whistleblower Questions Safety of Food Packaging
Former Employee Says Chemicals Come Off on Food
 
ABC News Investigation
 
Nov. 18, 2005
 
Could a Teflon chemical widely used in fast-food packages, candy wrappers, and microwave popcorn bags pose a health hazard?
 
A former DuPont senior engineer alleges the company long failed to disclose all it knew about the chemical. His allegations come as an environmental activist group has uncovered internal DuPont documents and provided them to the Food and Drug Administration for its review.
 
The FDA approved the chemical’s use in a wide range of food package in 1967. An FDA spokesman says the FDA has not changed its position that food packaging containing the chemical is safe for consumer use, but confirms that it is investigating the chemical’s safety.
 
Glen Evers, a 22-year veteran of DuPont, tells ABC News that DuPont failed to tell the FDA of internal studies showing that the chemical coating comes off food wrapping in greater concentrations than thought when the FDA first approved its use.
 
The chemical is widely used in the paper wrapping for fast foods such as french fries and pizza, as well as candy wrappers, microwave popcorn bags and other products. It helps to prevent grease stains from coming through the wrapper.
 
“You don’t see it, you don’t feel it, you can’t taste it,” Evers says. “But when you open that bag … and you start dipping your French fries in there, you are extracting fluorchemical … and you’re eating it.”
 
Once in the body, the chemical — zonyl — can break down into a chemical called PFOA. PFOA stays in the blood, a fact that was unknown when zonyl was first approved for use. The government says PFOA is now believed to be in the blood of nearly every American.
 
“It bioaccumulates, which means the chemical goes into the blood, and it stays there for a very long period of time,” says Evers.
 
Studies have linked PFOA to cancer, organ damage and other health effects in tests on laboratory animals. The Environmental Protection Agency currently is considering its safety in humans.
 
A DuPont memo from 1987, obtained by the Environmental Working Group, reveals test results that show the chemical zonyl was coming off food wrapping at three times the amount DuPont first thought it would.
 
“They never notified the FDA. They never said to the FDA, ‘We’re stopping our production of this product until we figure out what the problem is,’” Evers said.
 
DuPont is already under criminal investigation for failing to notify the government that PFOA might have been linked to birth defects of children born to workers at a DuPont plant in West Virginia.
 
“The documents that we are sending now to the FDA show that this is a pattern of cover-up and suppression,” said toxicologist Tim Kroop of the Environmental Working Group.
 
The company strongly denies any suggestion of a cover-up and insists the chemical is perfectly safe for use in food wrapping even though it does come off in small amounts. These small amounts, DuPont says, do not pose a health hazard. DuPont says it has “always complied with all FDA regulations and standards regarding these products.”
 
Evers is suing DuPont, asserting they fired him because of his opposition to some of their practices. DuPont says Evers “lost his job in a restructuring” and denies his allegations.
 
“DuPont thinks that they have pollution rights to the blood of every American, every man, woman and child in the United States,” says Evers.
 
ABC News’ Jill Rackmill, Dana Hughes and Rhonda Schwartz contributed to this report.
 
 
And we’re going for round two…. (And Americans believe that Russia is the problem?!!! America has lost their minds… The United States of Insanity…)

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Chasing Molecules excerpt explaining the ethylene tree branch of perfluorinated compounds. It’s our whole economic model that needs to be re-designed. Munition technologies have evolved significantly.

(Always remember that DuPont’s nickname was “The Merchants of Death” in the early 1900s for a reason)

Chapter 7: Out of the Frying Pan
Excerpt on Perfluorinated compounds (PFCs)

“This scenario of new materials with comparable intrinsic hazards being offered as alternatives to restricted products is now being repeated with perfluorinated compounds (PFCs). This is a family of compounds from an alphabet soup of names that are used to create non-stick, stain-repellant, and waterproof surfaces and films for both industrial and consumer applications—compounds so widely used that the EPA describes human exposure to these chemicals as “ubiquitous.” Perfluorinated compounds also provide an illustration of how difficult it is under our current chemical regulatory system to find out what is in a commercially marketed synthetic chemical even when it’s being used in contact with food or in products that touch our bodies. They also clearly demonstrate why it’s so important to ask questions about new materials’ biochemical behavior, molecular structure, and behavior—and not simply about performance and expedient production—as they’re being designed for a pharmaceutical or a frying pan.

Among this class of synthetic chemicals that we’ve been wrapping around food, sitting on, and wearing are substances that have been linked to impaired liver and thyroid function, immune and reproductive system problems, altered production of genetic proteins involved in cellular development, to tumor production in lab animals, and to elevated cholesterol levels in children, as well as to changes in metabolism, including how the body processes fat. These compounds are endocrine-disrupting properties and have been linked to cancer.

These perfluorinated chemicals—also sometimes referred to as perfluorocarboxylates (PFCAs) or fluoropolymers—are physically long chain molecules, made up predominantly of carbons and fluorines, in which the carbons are surrounded by fluorine atoms. (In chemistry, the prefix “per” describes a molecule that has the maximum amount of a particular element for its configuration. In the case of PFCs, each molecule has as many fluorine atoms attached as that structure can support.) Their varying lengths and structures depend on how, by whom, and for what purpose they are manufactured. This combination of elements makes strong, flexible, liquid-resistant, and slick-surfaced polymers. They are used as photoresist compounds in semiconductor manufacture, as fire-fighting foams, as insulation in plastics that sheathe wires and cables, as grease-resistant coating on pizza boxes, takeout food containers, microwave popcorn bags, and other packaging, including the support cards in candy and bakery items. They’re also used to make carpets, upholstery, and clothing fabrics (including leather) stain- and water-resistant—and are even added to toilet cleaner.

Among these compounds is one known as perfluorooctane sulfonate (FPOS). PFOA—made with eight carbon atoms and sometimes referred to as C8—is an ingredient of yet another per fluorinated compound called polytetrafluoroethylene (PFTE) that made up the original formulation of the products sold under the names Teflon, Gore-Tex, and Scotchguard. The structure that makes PFOA, PFOS, and PFTE so strong and durable also means that they resist degradation in the environment. They do so to such an extent that, like other persistent pollutants, they are chemical globetrotters. They are being found in Arctic animals, both fish and mammals—including polar bears—as well as in ice and snow. They’ve been found in Lake Ontario trout, in bird eggs collected along the Baltic Sea, in plant tissue, in mink liver, and in threatened and endangered sea turtles along the southern coast of the United States, including the Kemp’s Ridley sea turtle, now the scarcest of loggerhead sea turtles. Levels of PFOA and PFOS measured in sea otters along California coast reported in 2006 were the highest yet found in sea mammals.

While these fluoropolymers and the smaller molecules into which they break down are being found in remote locations and far from where their products were used or made, they are also being detected in human bio monitoring studies all around the world. Testing by the 3M Company—until 2000, itself a major PFOA producer—found PFCs in 95 precent of the Americans it surveyed, while researchers from the Center for Disease Control found such compounds in 98 percent of the Americans it tested. These compounds have even been found in fetal cord blood of newborn babies. These babies, part of a study conducted in Baltimore, Maryland, were also predominately low-birth-weight babies, suggesting that there may be a connection between PFC exposure and prenatal development. Subsequent studies found similar incidence of low birth weights in babies born to mothers in Denmark carrying PFOA in their blood. As has been observed in some PBDE studies, PFC levels in children taken from biomonitoring studies appeared to be higher that those in adults in the same studies. Given that PFOA can last years and that reexposure is almost certain under current conditions, it’s not surprising that children have been found to carry proportionally higher loads of these chemicals than do adults.

There are so many of these compounds at large in the environment and PFCs last so long that PFOA has now been detected in deep ocean environments in the Labrador Sea, which occupies a critical location in global ocean circulation and could send contaminants into either European or North American Arctic, thus extending their routes of potential exposure to people and wildlife. Factor in subsistence global warming in the far north and it’s likely these contaminants’ potential impacts will be felt more directly than in more southerly locations….

In late 2008, PFOA and PFOS were found in sewage sludge used as fertilizer on agricultural fields used for cattle grazing near Decatur, Alabama, where there was fear that the meat itself might be contaminated. The chemicals are thought to have originated in wastewater from nearby chemical manufacturing plants. Similar cases of PFC contamination of waterways and sludge have been reported across the United States and elsewhere around the world.

Meanwhile, workers at plants that produce PFCs have routinely been testing positive for these compounds. Such discoveries date back to 1978. Testing of DuPont workers done throughout the 1980s and the 1990s found elevated blood levels of PFOA and employees at DuPont’s West Virginia plant were found—in company studies—also to have higher than normal rates of leukemia, heart problems, atherosclerosis, and aneurysms. Women at a 3M plant who’d worked with these chemicals reported instances of birth defects in their children in the early 1980s, and in 1997 traces of PFOA and PFOS were reported in donated blood supplies…

There turn out to be a number of nonstick cookware lines now being sold under the banner of “PFOA-free.”…. There are a number of these PTFE-based “PFOA-free” products now being made by DuPont and other PFC manufacturers.

How, I wondered, could a material be “PFOA-free” yet made with polytetrafluoroethylene (PTFR)? For an explanation, I spoke to Olga Nadeinko, a senior scientist with the Environmental Working Group. These compounds are big, Christmas tree-like polymers, she says, explaining that “the carbon backbone of the molecule is the trunk of the tree and the side chains with the fluorine atoms are the branches.” PFOA is also known as C8 because it has eight carbon atoms from which its fluorine branches stem. One of the new perfluorinated compounds being used as an alternative to PFOA or C8, she explains is a compound known as perfluorohexanoic acid (PFHxA)—or C6, so named for the six carbon atoms in the molecules that make up the backbone or tree trunk of this PFC.

“What happens,” Nadeinko continued, “is that eventually the branches break off the tree” and these branches that form six-, seven-, and eight-carbon-chain molecules are among the perfluorinated compounds now being found in children and adults. “In the human body, PFOA can last two to fourteen years—on average five—and honestly, you don’t want it there,” says Nadeinko. And these fluorine branches, she points out, can break off PFC trees with six carbons in their initial formulation just as they can from those with eight carbons.

Yet DuPont, one of the several companies offering products based on C6 chemistry, states that these Capstone products “are based on short chain molecules that cannot break down to PFOA in the environment.” The technology used to produce this new product, we’re told, requires “negligible PFOA and PFOA precursor content.” While the company maintains that these products are not made with PFOA, it also says that it “believes that no one can substantiate statements that fluorotelomer products [the basis of chemistry] are ‘PFOA Free’ or have ‘Zero PFOA’ even if test results are below the limit of detection.” This circular statement would seem to indicate that while these products are being marketed as “PFOA-free,” they actually may contain—and therefore be made with—these compounds….

Toxic effects observed have resulted not only from C8 but also from exposure to C6, and it appears that very small amounts—in micro molar concentrations—can produce adverse effects… Scientists can now locate the precise genetic receptors where many such chemical interactions occur and have learned that certain synthetic chemicals have molecular compositions and structures that enable them to interact with the site where a hormone would bind. This has been discovered for a number of common synthetic chemicals, including bisphenol A and the other chemicals Bruce Blumberg of UC Irvine called “obesogens,” for dioxins, and for perfluorinated compounds.” – Chasing Molecules: Poisonous Products, Human Health, and the Promise of Green Chemistry by Elizabeth Grossman

 

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The Dark Side of the Perfectly Manicured American Lawn: Is It Giving You Cancer?  By McKay Jenkins from the book Contamination 

On a beautiful April day, I decided to meet outside with my students at the University of Delaware, where I teach journalism. We sat on the central lawn between two buildings that just happened to bear the names of two gargantuan chemical companies: DuPont and Gore. In the middle of a conversation about agricultural pesticides, a groundskeeper, dressed from feet to neck in a white chemical suit, drove by us on a mower. He wasn’t cutting the grass, though; he was spraying it. And not from one nozzle, but from half a dozen. Up and back he went, describing parallel lines as neat as those in any Iowa farmer’s cornfield. Not a blade escaped the spray. This became a perfect teaching moment.

“Who’s going to ask him what he’s spraying?” I asked my students. One young woman marched over to the groundskeeper. He turned off his engine, they spoke, and she returned.

“He said he’s spraying 2,4-D,” she said. “He said we didn’t need to worry, because he sprayed where we’re sitting at five this morning.”

Which would mean about seven hours earlier. My students chuckled uneasily. He was wearing a full-body chem suit, and they were sitting on the grass in shorts and bare feet?

They’d never heard of 2,4-D, or 2,4-dichlorophenoxyacetic acid. But they had heard of Agent Orange, the notorious defoliant used in Vietnam, and 2,4-D, one of the most extensively used herbicides in the world, is a constituent of Agent Orange (it did not cause the bulk of the devastating effects associated with Agent Orange). It was developed during World War II, mostly as a weapon to destroy an enemy’s rice crops. Despite its history, 2,4-D has long been seen as safe for consumer use.

In the 1940s, botanist E. J. Kraus of the University of Chicago fed five and a half grams of pure 2,4-D to a cow every day for three months. The cow was fine, according to Kraus, as was her calf. Kraus said he himself had eaten half a gram of the stuff every day for three weeks and felt great. This was apparently good enough for the rest of the country; within five years, American companies were annually producing 14 million pounds of the stuff. By 1964, the number had jumped to 53 million pounds.

Today, annual sales of 2,4-D have surpassed $300 million worldwide, and it’s found in “weed and feed” products, like Scotts Green Sweep, Ortho Weed B Gon, Salvo, Weedone, and Spectracide. At first, its impact on humans seems mild—skin and eye irritation, nausea, vomiting, dizziness, stiffness in the arms and legs—and many lawn-care companies have dismissed health concerns. Plus, the businesses add that the amount of chemicals in sprays is very diluted.

With 80 million home lawns and over 16,000 golf courses, you get close to 50 million acres of cultivated turf in America.

But the effects are more worrisome when considered over time. Because 2,4-D is designed to mimic a plant’s natural growth hormone, it causes such rapid cell growth that the stems of treated plants tend to become grotesquely twisted and their roots swollen; the leaves turn yellow and die; and the plants starve to death (2,4-D does not have this effect on grass).

Unsurprisingly, 2,4-D also appears to affect human hormones. The National Institute of Health Sciences lists it as a suspected endocrine disrupter, and several studies point to its possible contribution to reproductive-health problems and genetic mutations. Although the EPA says there isn’t enough evidence to classify 2,4-D as a carcinogen, a growing body of research has begun to link it to a variety of cancers.

A 1986 National Cancer Institute (NCI) study found that farmers exposed to 2,4-D for 20 or more days a year had a sixfold higher risk of developing non-Hodgkin’s lymphoma. Another NCI study showed that dogs were twice as likely to contract lymphoma if their owners used 2,4-D on their lawns.

Like flame retardants, this compound also tends to accumulate inside people’s homes even days after the lawn has been sprayed. One study found 2,4-D in the indoor dust of 63 percent of sampled homes; another showed that levels of the chemical in indoor air and on indoor surfaces increased after lawn applications. After 2,4-D was sprayed, exposure levels for children were ten times higher than before the lawns were treated—an indication of how easily the chemical is tracked inside on the little feet of dogs, cats, and kids.

Thanks to pressure from campus activists, my university replaced 2,4-D with “softer” herbicides and began putting signs on lawns that had just been sprayed. Of course, 2,4-D is one of scores of pesticides in use. According to David Pimentel, professor emeritus of entomology at Cornell University, 110,000 people suffer adverse health effects from pesticides every year, and 10,000 cases of cancer in humans may be attributable to pesticide exposure.

 

The Greening of America

In 1900, 60 percent of Americans lived in rural areas. Today, 83 percent live in cities or suburbs. With that change has come an astonishing shift in the landscape. Over the past half century, Americans have become obsessed with grass. When you add up the country’s 80 million home lawns and over 16,000 golf courses, you get close to 50 million acres of cultivated turf in the United States, an expanse roughly the size of Nebraska. This space is growing by 600 square miles a year.

By 1999, more than two thirds of America’s home lawns had been treated with chemical fertilizers or pesticides—14 million by professional lawn-care companies. A year later, the U.S. General Accounting Office reported that Americans were spraying 67 million pounds of synthetic chemicals on their grass every year, and annual sales of lawn-care pesticides had grown to $700 million.

The landscaping trucks rolling through our suburban neighborhoods seem to represent something more than a communal desire for lush grass. Could it be relief from anxiety? (Why else call a company Lawn Doctor?) For one thing, hiring lawn-care specialists is a public declaration that you have the money not to take care of your yard yourself.

Diligent lawn maintenance and chemical use are also associated with approval and social status, Ohio State researchers reported in 2012: “The main factor influencing a homeowner’s decision to use lawn chemicals is whether neighbors or other people in the neighborhood use them. Homeowners crave acceptance from their neighbors and generally want their lawns to fit in with their surrounding community, so they adopt their neighbors’ practices.”

We also create manicured lawns to play the most chemically dependent of pastimes: golf. By 2004, there were just under 15,000 golf courses in the United States—a patchwork of chemically treated turf the size of Rhode Island and Delaware combined.

Even grass seed comes coated with chemicals. A close look at a bag of Scotts grass seed reveals it has been treated with Apron XL fungicide, whose active ingredient is Metalaxyl-M, or methyl N-(methoxyacetyl)-N-(2,6-xylyl)-D-alaninate. The bag requests that the product be stored away from foodstuffs, kept out of the reach of children, and not be applied near water, storm drains, or drainage ditches. (A Scotts spokesperson says that its products are designed to be safe when used as directed.)

As the use of chemicals has become widespread, lawn companies have found an unexpected source of profits. Herbicides like 2,4-D preserve grass but kill weeds like clover. Clover, however, pulls nitrogen out of the air and fixes it in the soil. Without clover, soil becomes nitrogen poor and fails to support plant life. So chemical companies now replace the depleted nitrogen, which homeowners used to get for free from clover, with synthetic nitrogen, for which they have to pay.

In America’s watersheds, nitrogen runoff is considered among the worst problems for water quality. Since synthetic fertilizers are water soluble, a good amount runs off your lawn after a rain, where it mixes with runoff from other homes and ends up feeding the plants in bodies of water. Doused with chemicals, algae grow and grow, creating “algae blooms” that—as they decay and die—suck most of the oxygen out of rivers, lakes, and bays and lead to massive “dead zones,” in which neither fish nor plants can live.

In 2007, the Chesapeake Bay Foundation published a report card on the bay’s health that showed just how much trouble chemicals can pose. The bay received an F for nitrogen pollution, a D-minus for phosphorous, an F for water quality, an F for dissolved oxygen, and a D for toxics. On a scale of 100 (with 100 being the best), the bay’s health was rated at 28.

In California, scientists are discovering that algae blooms off the coast not only remove oxygen; they also release a toxin, domoic acid. It enters the food chain when fish eat algae, then moves into the sea lions that consume the fish. If a sea lion is pregnant, her fetus can be contaminated, and years later, that mammal may develop epilepsy.

 

One Man’s Chemical Conversion

Paul Tukey knows about pesticides; the man who invented 2,4-D was a distant cousin. When Tukey was a kid in the late 1960s, his grandfather hired a biplane to spray his 300 acres of fields in Maine a couple of times a year. The fields were mostly planted with cattle feed, not with crops intended for human consumption. For Tukey, spraying day was a thrill.

“My grandfather would go out in the field, dressed in his wool underwear and thick heavy pants, and wave the biplane over his field,” Tukey recalled. “They’d drop this white powder, and he’d get back in the truck looking like Frosty the Snowman. Then we’d drive to the next field, and he’d do it again. My grandfather was getting doused 20 times a day, but he would never let me get out of the truck. I always wondered why I couldn’t go out and get dusted.”

Tukey’s grandfather died of a brain tumor at 60.

Tukey also followed his family’s agricultural tradition but charted his own course. For years, he operated one of southern Maine’s largest landscaping services and considered his job ideal. He worked outside in shorts and sandals. He never bothered with putting on protective gear.

In 1993, he started getting nosebleeds. His vision became blurry. But with business booming, Tukey was too busy to worry. One of his jobs was tending the grounds of a hospital where he hired university students for the work. One day, their professor, an eminent horticulturist named Rick Churchill, came by to say hello to his students. Tukey went out to greet him.

Churchill’s eyes were focused on the weeds, which Tukey’s crew had doused with herbicides and which were curling up and turning brown.

Churchill said, “I asked him how anyone in good conscience could be applying pesticides on the grounds of a hospital where there were patients being treated for cancers that could be linked to their exposure to pesticides. I asked whether he knew anything about the toxicity ratings of what he was applying and how dangerous many of these compounds were to an individual compromised by illness.”

The words cut deeply. “It was devastating,” Tukey told me. “In Maine, Rick Churchill is an icon.”

“You have broken bags of poison,” Tukey told the manager. “They all say, ‘Keep out of reach of children’!”

Tukey did some reading, and what he found was troubling. Pediatric cancers in Los Angeles had been linked to parental exposure to pesticides during pregnancy. In Denver, kids whose yards were treated with pesticides were found to be four times more likely to have soft-tissue cancers than kids whose yards were not. Elsewhere, links had been found between brain tumors in children and the use of weed killers, pest strips, and flea collars.

Tukey also learned that exposure to lawn chemicals was particularly alarming for people who spread them for a living. One study showed a threefold increase in lung cancer among lawn-care workers who used 2,4-D; another found a higher rate of birth defects among the children of chemical appliers. When he finally went to the doctor for his rashes and deteriorating eyesight, he learned that he had developed multiple chemical sensitivity. And his son—conceived in 1992, during the height of Tukey’s use of synthetic chemicals—was diagnosed with one of the worst cases of ADHD his physician had ever seen. (Several recent scientific reports suggest that toxic chemicals may play a role in ADHD.)

“All the evidence indicates that you don’t want pregnant women around these products, but I was walking into the house every single night with my legs coated with pesticides from the knees down,” he said. “Even when my son was a year or two old, … [he] would greet me at the door at night by grabbing me around the legs. He was getting pesticides on his hands and probably his face too.”

Tukey’s Breaking Point

In the midst of his research, Tukey was driving one day when he saw a sign: A store was having a big sale on Scotts Turf Builder. Tukey made a beeline. He was going to buy the store’s entire stock. Once inside, he walked to the lawn-care section. Tukey noticed a woman standing by the lawn chemicals. At her feet, a girl was making sand castles from a broken bag of pesticides. Suddenly, something in him burst—the DDT squirting over his grandfather’s fields, the chemicals that he’d sprayed outside the hospital, and now a child in a pile of pesticides.

Tukey told me, “I said, ‘Ma’am, you really shouldn’t let your child play with that. It’s not safe.’ I’m fundamentally shy, but this just came out of me.”

The store wouldn’t sell the stuff if it wasn’t safe, she told Tukey. She took her child and walked away. A manager came up and asked him if there was a problem. Tukey said there was.

“You have broken bags of poison on the floor,” Tukey said to the manager. “All those bags say, ‘Keep out of reach of children’!”

Those labels are there because of government formality, the manager said. The stuff isn’t dangerous. The store wouldn’t carry it if it was.

“That really was the stake in the heart of my chemical career,” Tukey said. “By then, I’d already made myself sick. I’d already been questioned by Rick Churchill. When I saw that girl making sand castles out of the pesticides, [there] was just a sudden gut-level reaction I couldn’t have anticipated. I was shaking when I left the store.”

Tukey issued a decree to his employees: His business was going organic. It was time to start weaning his company—and customers—off synthetic chemicals. Most clients were fine with his decision, just as long as it didn’t cost any more and as long as their lawns continued to look the same.

More than 170 municipalities in Canada have banned lawn pesticides, especially on public spaces like school yards and sports fields. Denmark, Norway, and Sweden have banned 2,4-D. In 2009, the European Parliament passed laws banning 22 pesticides that can cause cancer or disrupt human hormones or reproduction.

 

How to Bring Back Butterflies

Certainly, switching to a less toxic lawn company can reduce your family’s—and neighbors’—exposure to synthetic chemicals. It would also reduce the pollutants you contribute to the watershed. But there is another option, one that gets into the more inspiring realm of restoration. There is a way to think of your yard as more than a burden that needs to be mowed and weeded. There is a way to think of your yard as transformational, even magical. Doug Tallamy can show you how.

When Tallamy, former chair of the entomology department at the University of Delaware, walks around his yard, he sees things most of us would not. He can look at a black cherry tree and spot the larvae of 13 tiger swallowtail butterflies. He has planted scores of trees: sweet gums, tulips, white oaks, river birches, and sugar maples. But he’s really interested in bugs and birds—and boosting their numbers.

Suburban development has been devastating to avian populations. Most of the birds we see in our yards are probably house sparrows and starlings, invasive species from Europe. If you study the population numbers for native birds, you’ll find the wood thrush is down 48 percent; the bobwhite, 80 percent; bobolinks, 90 percent. An estimated 72 million birds are killed each year in America by direct exposure to pesticides, a number that does not include baby birds that perish because a parent died from pesticides or birds poisoned by eating contaminated insects or worms. The actual number of birds killed might be closer to 150 million.

In mid-Atlantic gardening circles, Tallamy is a bit of a prophet, his message freighted with both gloom and promise. It is the promise of ecological renewal that he most wants people to understand. His vision is based on three ideas: If you want more birds, you need more native insects; if you want more native insects, you need more native plants; and if you want more native plants, you need to get rid of—or shrink—your lawn.

Tallamy says that when we wake up in the morning to birdsong, it’s often being made by hungry migratory birds that may have just flown 300 miles. What is there to eat? Too frequently, ornamental trees that bear none of the insects the birds need—and chemically treated grass. Tallamy’s prescription: Put in native plants that will make your yard a haven for caterpillars, butterflies, and birds. In the mid-Atlantic region, this can mean swamp milkweed, butterfly weed, buttonbush, joe-pye weed, and a rudbeckia species like black-eyed Susans. At the University of Delaware, Tallamy and a team are restoring native species to the campus.

And me? I ripped up 20 percent of my lawn and planted two flower gardens, two sets of flowering shrubs, and seven vegetable beds. Now my daughter helps me pick eggplants, tomatillos, okra, and Swiss chard. My son can identify not only monarchs and tiger swallowtails but also which plants they like to eat. How? Because last year the butterflies were not here, and this year they are. We replaced the grass, which monarch caterpillars can’t eat, with native flora they can consume. It’s as simple as that. Milkweed and joe-pye weed were born to grow here. All you have to do is plant them and wait for the butterflies.

 

Wise Moves for a Lush Lawn

1. Get tested. “Spending money on fertilizer without a soil test is just guessing,” says Paul Tukey. Good soil is key to a great lawn, and a soil test can tell you what’s in the dirt and what’s missing. For a test, call your county extension office (a national network of agriculture experts).

2. Plant clover with your grass. Clover competes with weeds and fixes nitrogen in the soil. John Bochert, a lawn and garden specialist in York, Maine, recommends a seed mix of white clover, perennial rye (it germinates quickly), fescue, and bluegrass.

3. Mow high, and leave the clippings. Taller grass provides more leaf for photosynthesis, develops deeper roots, and resists weeds. The clippings act as fertilizer. “Lawns mowed at four inches are the most weed-free,” Tukey says. “If you did only one thing, adjusting your mower height would be it.”

4. Cut back on watering. Frequent watering leads to shallow roots, so “water once a week if at all,” says Tukey

5. Apply compost. “Weeds need light to grow,” Tukey says. “Spreading compost on a lawn in the spring prevents weed seeds from germinating.”

6. Listen to weeds … “Weeds are nothing if not messengers,” says Tukey. “Dandelions are telling you the ground needs more calcium. Plantains are telling you the ground is too compact and needs aerating.”

7. … and to insects. Beneficial nematodes, which are microscopic worms, eat some 200 species of insects, including grubs that become Japanese beetles; you can buy them from farm and garden stores. Mix them in water, and spray them on your lawn.

 

 

 

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Effects of decabrominated diphenyl ether (PBDE 209) exposure at different developmental periods on synaptic plasticity in the dentate gyrus of adult rats In vivo.

Xing T1, Chen L, Tao Y, Wang M, Chen J, Ruan DY.
Author information

Abstract
Polybromininated diphenyl ethers (PBDEs) are widely used as flame-retardant additives. Previous studies have demonstrated that PBDEs exposure can lead to neurotoxicity. However, little is known about the effects of PBDE 209 on synaptic plasticity. This study investigated the effect of decabrominated diphenyl ether (PBDE 209), a major PBDEs product, on synaptic plasticity in the dentate gyrus of rats at different developmental periods. We examined the input/output functions, paired-pulse reactions, and the long-term potentiation of the field excitatory postsynaptic potential slope and the population spike amplitude in vivo. Rats were exposed to PBDE 209 during five different developmental periods: pregnancy, lactation via mother’s milk, lactation via intragastric administration, after weaning, and prenatal to life. We found that exposed to PBDE 209 during different developmental periods could impair the synaptic plasticity of adult rats in different degrees. The results also showed that PBDE 209 might cause more serious effects on the postsynaptic cell excitability in synaptic plasticity, and the lactation period was the most sensitive time of development towards PBDE 209.

http://www.ncbi.nlm.nih.gov/pubmed/19535737

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New battlefront for petrochemical industry: benzene and childhood leukemia by Kristen Lombardi for The Center For Public Integrity

ATHENS, Georgia — It was December 29, 1998, six years after Jill McElheney and her family had moved next to a cluster of 12 petroleum storage tanks. Jill was escorting her son Jarrett, then 4, to the doctor again. He had spent the day slumped in a stroller, looking so pale and fatigued that a stranger stopped her to ask if he was all right.

It was an encounter Jill couldn’t shake. For the previous three months, she had noticed her once-energetic preschooler deteriorating. He complained of pain in his knee, which grew excruciating. It migrated to his shoulder and then his leg. His shins swelled, as did his temples. At night, Jarrett awoke drenched in sweat, screaming from spasms. Jill took him to a pediatrician and an infectious-disease specialist. A rheumatologist diagnosed him with anemia.

Now, as Jarrett lay listless, Jill found herself back at the pediatrician’s office. Tests confirmed a blood count so low that she was instructed to get him to an emergency room immediately. Within hours she was at a hospital in Atlanta, some 65 miles from her home in Athens, watching nurses rush in and out of Jarrett’s room. Doctors identified a common form of childhood leukemia. “I heard the words,” Jill recalled, “and I only knew the bald heads and the sadness.”

In the waiting room, family members heard more unsettling news: A neighbor’s child also had developed leukemia.

Days later, Jarrett’s doctor penned a letter to federal environmental regulators about the two cancer patients, highlighting their “close proximity” to Southeast Terminals, a group of 10,000-gallon tanks containing gasoline, diesel and fuel oil.

“Could you please investigate,” the doctor wrote, “whether high levels of chemicals could have contaminated the water, possibly contributing … to the development of leukemia?”

Only then did the McElheneys consider the possibility that living beside one of the nation’s 1,500 bulk-oil terminals — known sources of cancer-causing benzene — had triggered their son’s leukemia.

“It was one of those light-bulb moments for us,” said Jeff McElheney, Jarrett’s father. “You never get over it.”

New battlefront for industry

Jarrett McElheney does not represent the standard benzene plaintiff. He’s not among the hundreds of thousands of people who toil in American oil refineries or other workplaces contaminated with the chemical and run the risk of developing leukemia. In the rancorous world of toxic-tort litigation, he stands virtually alone. A lawsuit filed by his parents in 2011 against Southeast Terminals owners BP and TransMontaigne is among a relatively few alleging leukemia caused by environmental benzene exposure. Among these, the McElheney case is rarer still: Most have hinged on adult leukemia.

Yet the case may signal an emerging quandary for the petrochemical industry, according to tens of thousands of pages of previously secret documents that have come to light in lawsuits filed against benzene manufacturers and suppliers on behalf of those who suffered from leukemia and other blood diseases, including Jarrett McElheney.

Internal memorandums, emails, letters and meeting minutes obtained by the Center for Public Integrity over the past year suggest that BP and four other major petrochemical companies, coordinated by their trade association, the American Petroleum Institute, spent at least $36 million on research “designed to protect member company interests,” as one 2000 API summary put it. Many of the documents chronicle a systematic attempt by the petrochemical industry to influence the science linking benzene to cancer. Others attest to the industry’s longstanding interest in topics such as childhood leukemia.

“A number of publications in the last few years have attempted to link increased risks of childhood leukemia with proximity to both petroleum facilities and local traffic density,” another 2000 API memo warns. “Although these publications have had little impact to date, the emphasis on ‘Children’s Health’ may cause these concerns to resurface.”

“This is indeed a battlefront for the oil industry,” said Peter Infante, a former director of the office that reviews health standards at the Occupational Safety and Health Administration, who has studied benzene for 40 years and now testifies for plaintiffs in benzene litigation. He has worked on a handful of cases involving children sickened by leukemia.

“It’s in the industry’s economic interests to refuse to acknowledge the relationship between benzene and childhood leukemia,” Infante said.

In May, in a sign of the chemical’s continuing threat, the U.S. Environmental Protection Agency estimated that 5 million Americans — excluding workers — face heightened cancer risks from benzene and 68 other carcinogens spewed into the air by the nation’s 149 oil refineries. The EPA has proposed a rule that would require refinery operators to monitor for benzene, in particular, along their fence lines.

Aimed at curbing “fugitive” emissions from equipment leaks and similar releases, the proposal would set a fence line limit for benzene of 3 parts per billion — a fraction of the 10 ppb the agency recommends as the maximum chronic exposure level for the chemical.

Industry groups are pushing back. In written comments, the API’s Matthew Todd called the proposal “a major and significant Agency action [that] will dramatically increase the paperwork and recordkeeping burden on refineries. It includes several precedent-setting proposals, will cost our industry hundreds of millions of dollars per year, increase safety risk [and] may impact fuels production and cost …. Production outages will likely occur.”

The EPA also heard from the people the rule is designed to protect. “We live near a refinery, and as a result my son can’t breathe,” a woman from Fontana, California, wrote in Spanish. “My cousin had respiratory problems while living near a refinery for more than 10 years,” a woman from Houston wrote, also in Spanish. “Unfortunately, he died 2 years ago from bone cancer. We believe this was a result of the ambient air where he lived.”

In June, California officials lowered the long-term exposure level for benzene from 20 ppb to 1 ppb — among the lowest in the country — setting the stage for further emissions cuts at refineries and bulk-oil terminals in that state. Officials say such regulatory actions aim to protect children, who are more susceptible to benzene’s toxic effects than adults because their cells aren’t as developed. California is considering classifying benzene not just as a human carcinogen, but as a “toxic air contaminant which may disproportionately impact children.”

“The fact that benzene impacts the blood-forming organs when you’re a developing child is a big deal,” said Melanie Marty of the state’s Office of Environmental Health Hazard Assessment.

Hidden menace

ill McElheney agrees. A warm, garrulous mother of five who has schooled herself in the health effects of pollution, she has spent the past 16 years seeking the cause of her son’s leukemia. She has filed open-records requests and contacted state and federal agencies, piecing together a history of gasoline spills and diesel-fuel leaks at Southeast Terminals. She can cite endless details about lingering benzene contamination on terminal property — extensively catalogued in state enforcement files — located “a stone’s throw away” from the trailer park where her family lived for seven years.

Jeff, Jarrett and Jill McElheney stand in the former site of the Oakwood Mobile Home Park, where the family was living when Jarrett was diagnosed with a form of childhood leukemia. Phil Skinner for the Center for Public Integrity
Now vacant and overgrown with brush, the former site of the Oakwood Mobile Home Park lies across a residential street from Southeast Terminals, its tanks rising above a thicket of pines and oaks. All day, every day, trucks drive in and out of the facility’s gates, filling tankers with gasoline and other products.

What can’t be seen is the plume of benzene that has worked its way into the groundwater beneath the tanks. “It’s not like Cancer Alley, with smokestacks belching crap in your face,” Jill said. “It’s hidden — literally.”

When she and Jeff moved to Oakwood in 1992, they saw the 14-trailer community as something of an oasis — quiet, tight-knit. Nestled under shady trees, near churches and schools, it seemed like the perfect location. Even the park’s water supply, drawn from an unpermitted well dating back decades, appeared idyllic: Its pump house served as a beacon on park property, visible for all to see — including, court depositions later confirmed, terminal employees.

“We saw Oakwood as an opportunity,” recalled Jeff, a mustachioed, genial man who operates a roofing company and managed the park for his father, its previous owner.

Jarrett McElheney, center, with 3 of his 4 siblings. Courtesy of the McElheney family
Jarrett arrived two years later and, by his fourth birthday, had grown into an adventurous boy with an abiding love of water. His parents remember him splashing in the tub for hours. Often, he swam in an inflatable pool in their yard, dressed in what he called his “little blue [wet] suit.” He slurped on Kool Aid and popsicles made from well water whose purity his parents never questioned — until his 1998 diagnosis of acute lymphocytic leukemia, or ALL, a form of the blood cancer found overwhelmingly in children.

Within days of hearing the news, Jarrett’s parents tested their water. Samples from the Oakwood well revealed a brew of such chemicals as carbon tetrachloride and 1,2-dichloroethane, sparking a state investigation. The Georgia Environmental Protection Division (EPD) found benzene in the water of Oakwood’s well at levels up to 13 ppb — 26 times higher than the federal safety standard. In response, the agency shuttered the well and connected residents to public water.

Over the next year, state geologists worked to identify the contamination’s source. They dug monitoring wells and collected soil samples. Their initial investigation linked at least one pollutant in the park well — not benzene — to nearby abandoned grain silos. Geologists eventually eyed Southeast Terminals as a likely source of the benzene contamination, records show.

“The terminals are certainly suspects for the benzene detected in the [Oakwood] well,” one posited in a 2000 email. “The probable path is deep ground water.”

Another noted the presence of “a possible plume (with benzene) moving by Oakwood … and within a few hundred feet of the [park]’s former well, [thus] too close for comfort for a public-water supply well.”

Two years later, EPD investigators were still documenting high levels of benzene, ranging from 8,000 to 12,000 ppb, on terminal property — as well as the likelihood that, one 2002 EPD memorandum states, “the benzene contamination found in the trailer park well came from the Southeast Terminals.”

Ultimately, though, the state’s two-year, nearly $200,000 investigation yielded few answers. By 2008, groundwater monitoring results revealed only trace amounts of benzene at Oakwood. Today, EPD officials say they lack definitive proof tying the well’s benzene pollution to any source.

For Jill McElheney, the outcome of the inquiry was anything but satisfying. “It just seems to me that when you’ve got benzene in a well and a major source of it next door, you’d make the connection,” she said.

In fact, Jill already had been seeking answers elsewhere. In 2000, she turned to the federal Agency for Toxic Substances and Disease Registry, or ATSDR, petitioning it for a public health assessment. Instead, the agency launched a less-thorough public health consultation, meant to ascertain the risk to human health posed by the contaminated well water at Oakwood.

The results brought little clarity. In a 2001 report, the ATSDR determined that “the groundwater contaminant plume” initially sampled in the Oakwood well “is a public health hazard.” At the same time, it singled out a pollutant other than benzene as the threat. For benzene, the agency found that “the likelihood someone would get cancer as a result of their exposure is very low.”

In a 2000 draft filed with the state, however, the ATSDR concluded that the highest concentrations of benzene in the water were of concern. “This risk DOES exceed an acceptable risk level,” the draft states, “and may result in an elevated risk of cancer for exposed individuals.”

An ASTDR spokeswoman did not respond to requests for comment.

Mounting evidence on benzene and leukemia

The science linking benzene to cancer — particularly leukemia, in all its forms — has preoccupied the petrochemical industry for more than half a century. As far back as 1948, the API’s toxicological profile of the chemical discussed “reasonably well documented instances of the development of leukemia as a result of chronic benzene exposure,” cautioning that “the only absolutely safe concentration … is zero.”

Later, as scientific evidence of benzene’s hazards accumulated and regulatory limits on workplace and environmental levels tightened, the industry took a different stance. By 1990, the API and member companies such as BP, Chevron, Mobil and Shell had launched a research program meant to keep further restrictions at bay — or, minutes from an API meeting in 1992 state, research “that will be most useful in improving risk assessment and influencing regulation.”

Within months, the API task force overseeing the program was enumerating “developing issues.” Topping its list, according to minutes from a meeting in 1993, was this notation: “link to childhood leukemia?”

That possible link appeared on the industry’s radar again in 2000, documents show. At the time, API representatives were drumming up financial support for an unparalleled study of workers exposed to benzene in Shanghai, China, delivering what amounted to a sales pitch for the project. They touted what one 2000 API overview described as its “tremendous economic benefit to the petroleum industry” — helping to combat “onerous regulations” and “litigation costs due to perceptions about the risks of even very low exposures to benzene.” Childhood leukemia was mentioned explicitly.

Five years later, industry representatives grew concerned enough to bankroll their own research. Documents show the API task force approved funding for what minutes of one meeting in 2005 dubbed a “benzene regulatory response,” comprising a “childhood leukemia review” and “child-to-adult sensitivity to benzene” analysis, for a total of $30,000.

By then, the scientific evidence on benzene and leukemia in adults was well-established. Throughout the 1960s and early 1970s, studies of Italian shoe and leather workers indicated a relationship between the chemical and the cancer. Then, in 1977, the National Institute for Occupational Safety and Health, part of the Centers for Disease Control and Prevention, launched a seminal study of two Goodyear plants in Ohio that made Pliofilm, a thin rubber wrap. The research quantified for the first time the leukemia risk for workers exposed to benzene, prompting OSHA to work on a stricter standard that took effect in 1987.

In years since, the science has solidified. Recent research has shown lower and lower levels of the chemical — less than the OSHA limit of 1 part per million — can cause leukemia as well as other blood and bone marrow disorders.

By contrast, experts say, the research on benzene and childhood leukemia isn’t as conclusive. Multiple studies have indicated that children whose mothers were exposed to benzene-containing solvents during pregnancy experience elevated risks of developing the disease. Others have shown that children living near gas stations or highways — breathing in benzene in the air — face heightened risks. One 2008 study reported a significant spike in the rate of the disease in Houston neighborhoods with the highest benzene emissions.

Taken together, the nearly four dozen publications on the topic strongly suggest the carcinogen can cause leukemia as much in children as adults, experts say.

“Children aren’t another species,” said Infante, the former OSHA official who has reviewed the scientific literature for medical associations and governmental agencies. “If benzene causes leukemia in adults, why wouldn’t it cause leukemia in children?”

The scientist behind the API-commissioned analysis would likely disagree. In 2009, David Pyatt, a Colorado toxicologist with long-standing ties to the petrochemical industry, published a journal article about his review, in which he reported examining 236 studies on the relationship between benzene and childhood leukemia. Many of the studies suggesting a link “suffer from the same limitations,” he concluded, such as poorly quantified exposure estimates.

“At this point,” Pyatt wrote, “there is insufficient epidemiologic support for an association or causal connection between environmental benzene exposure … and the development of childhood [leukemia].”

Some say the review reflects a common industry tactic: Compile studies on a subject, and then shed doubt on each one by claiming the data aren’t good enough.

Pyatt did not respond to repeated emails and phone calls from the Center seeking comment; nor did the API.

In depositions, Pyatt acknowledged that he has never testified for a plaintiff in a benzene exposure case. He has worked as a consultant and defense expert for such petrochemical giants as BP, ConocoPhillips, ExxonMobil and Shell, he has said; the API has financed additional work of his on benzene, as has the American Chemistry Council, the chemical industry’s main lobby.

In a deposition taken last year, Pyatt said he wouldn’t discount benzene’s link to childhood leukemia — at least, not to acute myeloid leukemia, or AML, a type rarely found in children.

“There is no reason to think that [children] are going to be protected,” he testified. “So I would certainly think that a child can develop AML if they are exposed to enough benzene.”

In other depositions, Pyatt has conceded no link between benzene and ALL, the type that attacked Jarrett McElheney.

‘They have to stop this practice’

For the McElheneys, the extent of the benzene contamination from Southeast Terminals only came to light years after Jarrett’s chemotherapy regimen had beaten back his leukemia. Yet state and federal enforcement records pinpoint on-site releases of the chemical in 1991, a year before the family moved to the area. At the time, managers of the terminal — jointly owned and operated by BP and Unocal Corp. — discovered a leak of diesel fuel seeping through soil where an underground pipeline was buried.

Terminal employees removed 40 cubic yards of “petroleum contaminated soils,” according to a report filed by BP with the state, and recorded benzene on site at levels as high as 81 ppb. Groundwater samples showed even higher concentrations: 12,000 ppb.

State regulators found such pollution “exceeds our ‘trigger’ levels,” a 1991 letter to the company states, and requested further action.

Under Georgia law, the company was required to develop what the EPD calls a “corrective action plan,” which, among other things, would have delineated the terminal’s benzene plume, as well as identified nearby public water wells.

In a 1991 reply, BP promised the EPD it would file its plan in four months.

Nine years later — after the McElheneys had tested their well water and the EPD had issued a 2000 citation against BP for failing to submit a “timely” corrective action plan — the company finally carried out that requirement, records show.

BP, in charge of the terminal’s daily operations, declined to comment for this article. At different times, Unocal, Louis Dreyfus Energy and TransMontaigne have been BP’s partners at the site. TransMontaigne, its current partner, did not respond to repeated emails and phone calls. TransMontaigne purchased Louis Dreyfus Energy in 1998. Chevron, which merged with Unocal in 2005, declined to comment.

Today, state regulators attribute their own delay in cracking down on the diesel leak to an internal debate over which EPD division had authority over the terminal’s benzene contamination — its underground storage tank program, which has purview over the pipeline; or, its hazardous waste branch. For years, compliance officers in that branch, along with their counterparts at the EPA, had been monitoring the facility’s practice of dumping benzene-laced wastewater on site — a practice later confirmed by terminal employees in court depositions.

In 1990, the EPA issued new rules classifying benzene as hazardous waste and requiring bulk-oil terminals to have permits for discharging the “bottoms water” in petroleum tanks. This wastewater can become tainted by the chemical when mixed with gasoline. Rather than treat the water, Southeast Terminals funneled it through an “oil/water separator” to skim off fuel, and then dumped it into a ditch on the ground.

Company records at the time show that terminal supervisors admitted they drained the wastewater “direct into streams” or “a dike area which eventually drains offsite into a stream.”

“I remember thinking, ‘They have to stop this practice,’” said John Williams, an EPD environmental specialist who inspected the terminal in 1993 and documented the dumping.

Three months later, the EPD issued a notice of violation against Southeast Terminals, forcing supervisors to test the bottoms water. Regulators found benzene at levels four times greater than the legal limit of 0.5 ppb, prompting the EPA to take action.

“We saw an issue there,” said Darryl Hines, of the EPA’s regional office in Atlanta, explaining why officials initiated a 1997 civil enforcement action against the facility.

In its complaint, the EPA accused BP and then-partner Louis Dreyfus Energy of violating federal hazardous-waste law — disposing waste without a permit, and failing to categorize it as hazardous. The agency ordered the companies to shut down the oil/water separator, and implement a plan addressing “any groundwater contamination.”

By the time Jarrett developed leukemia a year later, the EPA had negotiated a settlement with the companies and laid out a series of requirements for cleaning up the benzene. Without admitting fault, BP and Louis Dreyfus agreed to spend at least $100,000 to remove leaking underground pipelines and install above-ground infrastructure. They also paid a penalty of $15,000.

When BP finally filed its long-delayed action plan, it revealed the presence of what EPD project officer Calvin Jones described as a “dissolved hydrocarbon” plume containing benzene — “a bigger problem than we had thought.” The chemical, concentrated at 500 ppb and counting, had spread beyond the immediate spill areas. Of greater concern to regulators, the plan identified “free product” in groundwater.

“There was actually gasoline floating on the water,” explained Jones, of the EPD’s underground storage tank program, who oversaw the facility’s protracted cleanup. Referring to gasoline’s ability to dissolve in water, he said, “You can’t get higher concentrations of benzene … than free product.”

Despite a decade-long cleanup — 35.2 million gallons of contaminated groundwater and 1,009 pounds of benzene were collected — the chemical still saturates much of the nearly 19-acre Southeast Terminals site, records show. Last year, the EPD issued a letter declaring “no further action required,” which released the companies from remediation. At the time, the state-sanctioned benzene count remained at 1,440 ppb.

Over the years, enforcement records show, company consultants and regulators alike have tried to trace the path of the wastewater at the terminal. One company analysis details a trail beginning at the property line and then spilling into adjacent woods before hitting a tributary. Another document, produced by the EPA, depicts the discharge as moving offsite through woods and into a resident’s backyard.

“It’s where the drainage flows,” said Jeffrey Pallas, deputy director of the agency’s hazardous waste division in Atlanta, who oversaw the case against BP and Louis Dreyfus, explaining that the document, complete with photographs, was only intended to verify the hazardous-waste law violations.

“We cannot substantiate from the documentation we have that the benzene left the site,” he said.

Seeking accountability

The McElheneys have seen the evidence they need to connect Southeast Terminals to the benzene in the Oakwood well — and Jarrett’s suffering. They believe all the state and federal enforcement actions have yielded few consequences for the facility’s owners. If Jarrett hadn’t gotten sick, they say, they might never have known about the benzene hazard. “The companies would have paid off their small fines,” Jill said, “and nobody would have been the wiser.”

Seeking some accountability, the family filed a lawsuit three years ago against BP, TransMontaigne and seven other previous owners, alleging that the “illegal discharge and release of toxic chemicals” at Southeast Terminals contaminated the surrounding environment and caused Jarrett to develop leukemia.

In court filings, the companies denied the allegations and dismissed any link between benzene and childhood leukemia. Last year, defense lawyers invoked a familiar tactic: They cited the Pyatt review to support their claims that the chemical couldn’t have caused Jarrett’s illness. The family recently has agreed on a settlement in principle and is working toward resolving the litigation.

“I thought, ‘This is par for the course,’” said Jill, who has read some of the industry documents uncovered by the lawsuit. “The oil industry has fought regulations and lawsuits for workers and adults. Now they’re going to do it with children.”

Jarrett is now a slight, reserved 20-year-old in remission. He remembers his bout with leukemia through a child’s eyes — the “really cool” ambulance rides, the nurses with coloring books, swinging golf clubs in hospital hallways. “I remember being stuck over and over again by needles” while getting a bone-marrow aspiration or a chest catheter or countless blood draws, he said. “But it wasn’t until much later I realized what happened to me didn’t happen to other kids.”

Today, he has had to grapple with cancer’s lasting effects — the feebleness, and the fatigue — as well as its lingering fears. As a leukemia survivor, he is at risk for developing osteoporosis, cataracts, or even another cancer. Sitting in an Olive Garden in Athens, sandwiched between his parents, Jarrett came across as exceedingly shy, uncomfortable in the limelight. Often, his parents did the speaking for him.

Moments earlier, Jill had explained how leukemia had changed her son, taken an emotional toll.

“He had a really loud voice as a toddler but that voice has mellowed,” she said. “I’ll take that voice over anything.”

Maryam Jameel contributed to this story.

Click on the link below to access the original article at the Center for Public Integrity

http://www.publicintegrity.org/2014/12/08/16356/new-battlefront-petrochemical-industry-benzene-and-childhood-leukemia

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A dozen dirty documents
Twelve documents that stand out from the Center’s new oil and chemical industry archive

By Kristen Lombardi for The Center for Public Integrity

The Center for Public Integrity, along with researchers from Columbia University and the City University of New York, on Thursday posted some 20,000 pages of internal oil and chemical industry documents on the carcinogen benzene.

This archive, which will grow substantially in 2015 and beyond, offers users a chance to see what corporate officials were saying behind the scenes about poisons in the workplace and the environment.

Here are 12 examples of what the petrochemical industry knew about benzene; the impetus behind industry-sponsored science; and the corporate spin that often occurs when damning evidence against a chemical threatens companies’ bottom lines.

What the industry knew:

The industry knew the dangers of benzene exposure at both high and low concentrations, as illustrated by this 1943 report for Shell Development Company by a University of California researcher.

“Inasmuch as the body develops no tolerance to benzene, and as there is a wide variation in individual susceptibility, it is generally considered that the only absolutely safe concentration for benzene is zero.” That was a conclusion reached in a 1948 toxicological review of benzene prepared for the American Petroleum Institute, a trade association.

Benzene’s dangers known in 1943 (pg 2)
This 1943 report, prepared for Shell, is among the earliest to suggest that any prolonged exposure to benzene may be harmful.

No safe exposure level (pg 4) This 1948 review, prepared for the oil industry’s main trade group, the American Petroleum Institute, continues to torment the industry in litigation alleging benzene can cause various types of leukemia and other diseases of the blood-forming organs. In essence, it says the chemical is so potent that there is no safe exposure level.

A 1950 consultant’s memo to Shell lists benzene as having “established carcinogenic qualities.”

Benzene recognized as a well-known carcinogen (pg 1)

This 1950 memorandum from a consultant for Shell Development Company notes that benzol — an obsolete name for benzene — is a well-known carcinogen. As the author states, the memo was prompted by “an increased concern about the incidence of cancer” among Shell workers.

Motivations for industry involvement in research:

In 1995, a benzene study by the National Cancer Institute caught the attention of Exxon scientists, who closely monitored it.

Industry interest in cancer research (pg 1)
An Exxon scientist, B.F. Friedlander, explains that he and industry colleagues are “monitoring” a series of studies by the National Cancer Institute because of their focus on “health risks at low benzene exposures.” The memo shows the petrochemical industry’s early interest in the work of the NCI, which has examined the effects on Chinese workers exposed to benzene at levels below the legal occupational limit in the United States.

While attempting to gain support for a proposed study of benzene toxicity in Shanghai, China, the American Petroleum Institute cites “a tremendous economic benefit” to companies, which could gain data to combat “onerous regulations.” A project overview explains that publications linking benzene to childhood leukemia may cause concerns about the chemical to “resurface.”

‘Tremendous economic benefit’ from the industry study (pg 1)
The six-page overview touts the proposed Shanghai research as a way for the petrochemical industry to gain an “accurate understanding” of benzene’s health effects, which, in turn, would bring “tremendous economic benefit.”

A 2000 summary of the API’s research strategy, drafted by the group’s Benzene Task Force, explains that the research program “is designed to protect member company interests.” The anticipated results could “significantly ameliorate further regulatory initiatives” to curb benzene emissions.

Protecting industry interests (pg 2)

The summary describes the intent of the API’s research program as being “designed to protect member company interests.”

An email exchange explains how “HSE [health, safety and environment] issues surrounding benzene as well as the litigation claims” against the industry compel companies to participate in the industry-sponsored study.

Motivations for research (pg 2)
An email from one Shell executive argues that the “litigation claims we continue to see” are prime reasons for the company to spend millions of dollars on the proposed Shanghai research.

A PowerPoint presentation from 2001 lists “significant issues of concern” to encourage financial support for the API’s research on benzene-exposed workers in China. Among them is “litigation alleging induction of various forms of leukemias and other hematopoietic diseases.” The study, according to the presentation, could provide “strong scientific support for the lack of a risk of leukemia or other hematological diseases at current ambient benzene concentrations to the general population.”

Significant issues of concern (pg 3)
This PowerPoint slide suggests “significant issues of concern” that the proposed Shanghai research might help combat, which would save the petrochemical industry “millions of dollars in expenses.” The issues include more stringent regulations and litigation from benzene exposure.

“Litigation support” and “risk communication” are listed as goals in this 2007 memorandum describing an API risk management program. Further objectives are to establish current regulations as “protective” and avoid additional action.

Oil lobby’s risk management program (pg 1)
The memorandum details the oil lobby’s benzene “risk management” program, intended to “develop scientific data” for it and its member companies to use for “science advocacy” and “litigation support.”

Corporate spin

An undated litigation defense guide written by a senior Shell attorney acknowledges the 1948 report on leukemia and offers a “comprehensive strategy” on how to respond to litigation, including releasing benzene-related documents only on court order.

Acknowledgement of the science showing no safe levels of benzene (pg 4)

Here the author, Richard O. Faulk of Shell Oil’s legal department, references a 1948 Toxicological Review prepared for the American Petroleum Institute. The review found that “the only absolutely safe concentration for benzene is zero.”

After a draft of an API recruitment brief reminds potential study sponsors of “personal injury claims,” an email exchange among members of the Benzene Health Research Consortium urges deletion of “the reference to legal liabilities.”

Don’t mention the legal liabilities (pg 3)

This email from a Shell executive responds to an attached draft of a 2002 recruitment brief that reminds prospective donors about benzene liability costs. In the email, the executive urges colleagues to delete “the reference to legal liabilities” and emphasizes that “the only reason we are doing this is in support of protecting workers.”

A 2001 email from the consortium’s communications committee explains that the perception of the study “needs to be that this is not being done to protect against litigation”

Controlling the message on benzene (pg 1)

The email shows the companies behind the Benzene Health Research Consortium working hard to control their message. It lays out the “scope of public affairs” for the consortium’s communications committee, which includes countering any “perception” that the Shanghai study was “done to protect against litigation.”

Click on the link below to access original article and archival documents.

http://www.publicintegrity.org/2014/12/05/16361/dozen-dirty-documents

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Internal documents reveal industry ‘pattern of behavior’ on toxic chemicals by David Heath for The Center for Public Integrity

Sixty-six years ago, a professor at the Harvard School of Public Health wrote a report linking leukemia to benzene, a common solvent and an ingredient in gasoline. “It is generally considered,” he wrote, “that the only absolutely safe concentration for benzene is zero.”

The report is remarkable not only because of its age and candor, but also because it was prepared for and published by the oil industry’s main lobby group, the American Petroleum Institute.

This document and others like it bedevil oil and chemical industry executives and their lawyers, who to this day maintain that benzene causes only rare types of cancer and only at high doses.

Decades after its release, a lawyer for Shell Oil Company flagged the 1948 report as being potentially damaging in lawsuits and gave out instructions to “avoid unnecessary disclosure of sensitive documents or information” and “disclose sensitive benzene documents only on court order.”

Plaintiff’s lawyers like Herschel Hobson, of Beaumont, Texas, wield such documents in worker exposure cases to demonstrate early industry knowledge of benzene’s carcinogenic properties.

“It shows a pattern of behavior,” Hobson said. “It shows how industry didn’t want to share bad news with their employees. None of this information was made available to the average worker … Most of this stuff kind of gets lost in the weeds.”

No more. Today, the Center for Public Integrity; Columbia University’s Mailman School of Public Health and its Center for the History and Ethics of Public Health; and The Graduate Center at the City University of New York are making public some 20,000 pages of benzene documents — the inaugural collection in Exposed, a searchable online archive of previously secret oil and chemical industry memoranda, emails, letters, PowerPoints and meeting minutes that will grow over time.

The aim is to make such materials — most of which were produced during discovery in toxic tort litigation and have been locked away in file cabinets and hard drives — accessible to workers, journalists, academic researchers and others.

Some are decades old, composed on manual typewriters; others are contemporary. Combined with journalism from the Center — such as today’s story on a $36 million benzene research program undertaken by the petrochemical industry — and articles and papers from Columbia and CUNY faculty and students, the archives will shed light on toxic substances that continue to threaten public health.

Exposed: Decades of denial on poisons

The benzene documents are just the start. In coming months, we’ll be posting hundreds of thousands of pages of discovery material from lawsuits involving lead, asbestos, silica, hexavalent chromium and PCBs, among other dangerous substances. And we’ll be on the lookout for other documents.

The inspiration for the project came when we realized that in CPI’s reporting on environmental and workplace issues, we routinely obtained reams of court documents. Often, these documents hold secrets found nowhere else.

Last year we reached out to William Baggett Jr., a lawyer in Lake Charles, Louisiana, who had acquired more than 400,000 pages of documents from a decade-long case against manufacturers of vinyl chloride, a cancer-causing chemical used in plastics. Baggett agreed to give us all of them.

At the same time, public health historians Merlin Chowkwanyun, David Rosner and Gerald Markowitz were collecting court documents to create a public database and had approached Baggett. We decided to collaborate. Chowkwanyun is currently a Robert Wood Johnson Foundation Health & Society Scholar at the University of Wisconsin-Madison, and will be an assistant professor of sociomedical sciences at Columbia next year. Rosner is Ronald Lauterstein Professor of Sociomedical Sciences and History at Columbia. Markowitz is a professor of history at the City University of New York. Both Rosner and Markowitz have served as expert witnesses in a number of major cases related to these documents and have written Deceit and Denial: The Deadly Politics of Industrial Pollution and other books and articles based on them.

This is not the first database of its ilk. The University of California, San Francisco, maintains a massive collection of documents from tobacco-related lawsuits called the Legacy Tobacco Documents Library, which exceeds 80 million pages.

How to search the documents

Our database allows you to search for a word, combination of words or an exact phrase in any of the documents. You can also:

Do a search that excludes a word by putting a ‘-‘ sign in front of the word.
Do a fuzzy search that includes variations of a word by putting a tilde ‘~’ at the end of a word with the numbers of characters that don’t have to match exactly. For example, ‘planit~2’ will match ‘planet.’
Do a search that optionally contains a word by putting a ‘|’ between the words.
Do a search with a phrase by putting double quotes around the phrase.
Each document will include the court case from which it came, including the case title, case number, court as well as date filed and date terminated. The original complaint for each lawsuit is also part of the database.

Soon, we will make available a robust set of text-mining tools that will allow researchers to construct chronologies of documents; generate lists of common words, phrases and names; and sort documents in a number of ways. Qualified researchers will also have access to an even larger set of documents that will eventually contain millions of pages.

Robert Proctor, a professor of the history of science at Stanford, has used the UCSF tobacco archive extensively to do research for several books. He called it “an unparalleled treasure” that gives researchers the ability “to look through the keyhole of the mansion of this hidden world and see [corporate officials’] private thoughts, their intent, their ruminations, their jokes, their plans, how they treat their workers, how they treat the public…”

Proctor said he sees value in a similar archive on toxic chemicals. “The internal records of the chemical industry are known only to a tiny group of lawyers and journalists,” he said. “This is going to create a new kind of democracy of knowledge. It also will set the stage for whistleblowers to come forward with documents.”

That’s our hope. The search interface includes options to send us documents or contact us. The ultimate goal, to borrow Proctor’s phrasing, will be to give users “a strong magnet to pull rhetorical needles out of archival haystacks.”

Click on the link below to access the original article at The Center for Public Integrity

http://www.publicintegrity.org/2014/12/04/16330/internal-documents-reveal-industry-pattern-behavior-toxic-chemicals

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Burning irony: Flame retardants might create deadlier fires by By Brett Israel
http://www.environmentalhealthnews.org/ehs/news/2012/burning-irony
Senior Editor and Staff Writer Environmental Health News
April 4, 2012

In one of the deadliest nightclub fires in American history, 100 people died at a rock concert in Rhode Island nearly a decade ago. But the biggest killer wasn’t the flames; it was lethal gases released from burning sound-insulation foam and other plastics.

In a fatal bit of irony, attempts to snuff fires like this catastrophic one could be making some fires even more deadly.
New research suggests that chemicals – brominated and chlorinated flame retardants – that are added to upholstered furniture and other household items to stop the spread of flames increase emissions of two poisonous gases.
“We found that flame retardants have the undesirable effect of increasing the amounts of carbon monoxide and hydrogen cyanide released during combustion,” study co-author Anna Stec, a fire specialist at the University of Central Lancashire in the United Kingdom, said in a statement.

These two gases are by far the biggest killer in fires. They are responsible for 60 to 80 percent of fire deaths, according to the National Fire Protection Assn. During the Rhode Island fire, the levels of hydrogen cyanide and carbon monoxide were high enough to kill in less than 90 seconds. (There is no evidence, however that flame retardants were involved; the nightclub’s foam insulation reportedly was not treated with them.) [Editor’s note: clarification added 4/5/2012]

Flame retardants made of brominated or chlorinated chemicals are added to furniture cushions, carpet padding, children’s car seats, plastics that encase electronics and other consumer items. Under California standards adopted in the 1970s, foam inside furniture must withstand a 12-second exposure to a small, open flame, and much of the nation’s furniture is manufactured with flame retardants to meet that standard.

However, while the chemicals may be slowing the spread of flames, when fires do occur, they may be more deadly. Few details of the new research from the United Kingdom are available since the findings have not yet been published. But the researchers said in one experiment, nylon containing the flame retardant brominated polystyrene released six times more hydrogen cyanide when set afire than the same material containing a halogen-free flame retardant.

Hydrogen cyanide is 35 times more deadly than carbon monoxide, and during a fire it can kill in as little as one minute, said Todd Shoebridge, a 30-year fire service veteran who is a captain at the Hickory Fire Department in North Carolina. “It’s that serious,” Shoebridge said.

Both carbon monoxide and hydrogen cyanide are products of incomplete combustion. As a room on fire loses oxygen, combustion becomes less efficient and gases and smoke rapidly increase. Inhaling the toxic air becomes unavoidable for people trapped in a fire.

Brominated and chlorinated flame retardants work by interfering with combustion, which can increase the amount of the gases.

The evidence “leads one to assume that these chemicals could increase fire safety concerns, not decrease them,” said Heather Stapleton, an environmental chemist at Duke University who specializes in studying brominated compounds.
The new research focused on brominated polystyrene, a newer flame retardant manufactured by Albemarle Corp. and other companies. It is added to nylon for use in textiles, upholstery and electrical connectors.

These newer compounds were designed to replace older flame retardants, mostly polybrominated diphenyl ethers or PBDEs, which have been banned since 2004 because they were building up in human bodies, including breast milk. PBDEs are still found in furniture manufactured before the bans.

PBDEs and other halogenated flame retardants were already known to produce other toxic chemicals when they burn, including highly toxic dioxins and furans.

Another replacement for PBDEs is called Tris or TDCPP, (1,3-dichloroisopropyl) phosphate. Foam containing this chemical was shown to release high amounts of carbon monoxide and smoke during ignition, according to a 2000 study.

With or without fires, research suggests, flame retardants may have risks. PBDEs and other halogenated flame retardants have come under intense scrutiny in recent years. PBDEs have been linked in some studies of people and animals to impaired neurological development, reduced fertility, early onset of puberty and altered thyroid hormones. Tris also may be toxic to the developing nervous system.

Albemarle Corp., based in Baton Rouge, La., and maker of Saytex 3010G, a brominated polystyrene flame retardant similar to mixtures tested in the new research, did not return requests for comment. Chemtura Corp., another flame retardant manufacturer based in Philadelphia, Penn., also did not return requests.

The companies have maintained that flame retardants play a critical role by allowing longer escape and response times during a fire, thereby saving lives and property.

“It is estimated that escape times can be up to 15 times longer when flame retardants are present, providing increased survival chances,” according to a statement from the European Brominated Flame Retardant Industry Panel, which includes Albemarle and Chemtura.
[Editor’s note: Additional information from industry was available and added on 4/5/2012]

Bryan Goodman, a spokesman for the American Chemistry Council, which represents chemical companies, called the claim that flame retardants may increase fire deaths “irresponsible, as it ignores important research.”

“Scientists have long pointed out that when flame retardants are included in upholstered furniture it slows or stops fires, thereby causing less burn, fewer flames, less smoke and fewer toxic gases,” he said. “This fact has been proven in large scale tests of upholstered furniture.”

Goodman said the new research “used a small-scale test, which is not representative of what one would find in a real fire.”

But a document signed by more than 200 scientists from 30 countries disputes that flame retardants have been proven effective. “Brominated and chlorinated flame retardants can increase fire toxicity, but their overall benefit in improving fire safety has not been proven,” the 2010 statement says.

The health threats from halogenated flame retardants combined with their persistence in the environment have driven a search for more environmentally friendly alternatives.

“Reducing the use of toxic or untested flame retardant chemicals in consumer products can protect human and animal health and the global environment without compromising fire safety,” says a 2010 report by a group of 10 scientists, including Linda Birnbaum, director of the National Institute of Environmental Health Sciences.

In the new research from the United Kingdom, some alternatives were found to create less toxic air than the halogenated flame retardants. Inorganic, or mineral-based, flame retardants had little effect on toxic gases released in a fire.
Each year, about 10,000 people die in fires in industrialized countries. On average in the United States in 2010, someone died in a fire every 169 minutes, according to the National Fire Protection Assn.

Previous research has focused on carbon monoxide and soot from halogenated flame retardants. But lately, hydrogen cyanide and other gases are getting a closer look, said Richard Hull, a chemist at the University of Central Lancashire who presented the new flame retardant research at an American Chemical Society conference in San Diego last week.

“Carbon monoxide is an important toxicant in fire effluents. However, we have seen that it is less important than hydrogen chloride from burning PVC, or hydrogen cyanide from burning nitrogen-containing polymers such as nylon, polyurethane or acrylic, in developed fires,” Hull said.

New research has suggested that hydrogen cyanide – so lethal it was used in the Nazi gas chambers – is a bigger cause of fire deaths than previously thought.

In one example, a fire devastated a prison in Buenos Aires, Argentina, in 1990. Thirty-five inmates died as a mattress fire spread through the prison. But flames did not kill the convicts, a post-mortem blood analysis revealed. Hydrogen cyanide did.

“The results indicated that death in the 35 fire victims was probably caused by HCN [hydrogen cyanide], generated during the extensive polyurethane decomposition provoked by a rapid increase of temperature,” according to the analysis of the victims in the Argentina fire.

Hydrogen cyanide and carbon monoxide are odorless, colorless chemicals, making them silent killers.
“If there is a fire, it doesn’t matter how big or how small,” said Shoebridge, who is lead advocate of North Carolina’s “Everybody Goes Home” firefighter safety program. “You have the possibility for those gases.”

http://www.environmentalhealthnews.org/ehs/news/2012/burning-irony

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Some Flame Retardants Make Fires More Deadly – ScienceDaily (Mar. 27, 2012)
http://www.sciencedaily.com/releases/2012/03/120327134240.htm

Some of the flame retardants added to carpets, furniture upholstery, plastics, crib mattresses, car and airline seats and other products to suppress the visible flames in fires are actually increasing the danger of invisible toxic gases that are the No. 1 cause of death in fires. That was the finding of a new study presented in San Diego on March 27 at the 243rd National Meeting & Exposition of the American Chemical Society (ACS), the world’s largest scientific society. Anna A. Stec, Ph.D., led the research, which focused on the most widely-used category of flame retardants, which contain the chemical element bromine. Scientists term these “halogen-based” flame retardants because bromine is in a group of elements called halogens.

Some of the flame retardants added to carpets, furniture upholstery, plastics, crib mattresses, car and airline seats and other products to suppress the visible flames in fires are actually increasing the danger of invisible toxic gases that are the No. 1 cause of death in fires. That was the finding of a new study presented in San Diego on March 27 at the 243rd National Meeting & Exposition of the American Chemical Society (ACS), the world’s largest scientific society. Anna A. Stec, Ph.D., led the research, which focused on the most widely-used category of flame retardants, which contain the chemical element bromine. Scientists term these “halogen-based” flame retardants because bromine is in a group of elements called halogens.

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Tribune Watchdog – Playing with Fire Series
http://media.apps.chicagotribune.com/flames/index.html

Chemical companies, Big Tobacco and the toxic products in your home.

The average American baby is born with 10 fingers, 10 toes and the highest recorded levels of flame retardants among infants in the world. The toxic chemicals are present in nearly every home, packed into couches, chairs and many other products. Two powerful industries — Big Tobacco and chemical manufacturers — waged deceptive campaigns that led to the proliferation of these chemicals, which don’t even work as promised.

INDUSTRY DECEPTION
PART 1 – TORCHING THE TRUTH

Fear fans flames for chemical makers

By Patricia Callahan and Sam Roe, Chicago Tribune reporters
May 6, 2012

Dr. David Heimbach knows how to tell a story.

Before California lawmakers last year, the noted burn surgeon drew gasps from the crowd as he described a 7-week-old baby girl who was burned in a fire started by a candle while she lay on a pillow that lacked flame retardant chemicals.

“Now this is a tiny little person, no bigger than my Italian greyhound at home,” said Heimbach, gesturing to approximate the baby’s size. “Half of her body was severely burned. She ultimately died after about three weeks of pain and misery in the hospital.”

Heimbach’s passionate testimony about the baby’s death made the long-term health concerns about flame retardants voiced by doctors, environmentalists and even firefighters sound abstract and petty.

But there was a problem with his testimony: It wasn’t true.

Records show there was no dangerous pillow or candle fire. The baby he described didn’t exist.

Neither did the 9-week-old patient who Heimbach told California legislators died in a candle fire in 2009. Nor did the 6-week-old patient who he told Alaska lawmakers was fatally burned in her crib in 2010.

Heimbach is not just a prominent burn doctor. He is a star witness for the manufacturers of flame retardants.

His testimony, the Tribune found, is part of a decades-long campaign of deception that has loaded the furniture and electronics in American homes with pounds of toxic chemicals linked to cancer, neurological deficits, developmental problems and impaired fertility.

The tactics started with Big Tobacco, which wanted to shift focus away from cigarettes as the cause of fire deaths, and continued as chemical companies worked to preserve a lucrative market for their products, according to a Tribune review of thousands of government, scientific and internal industry documents.

These powerful industries distorted science in ways that overstated the benefits of the chemicals, created a phony consumer watchdog group that stoked the public’s fear of fire and helped organize and steer an association of top fire officials that spent more than a decade campaigning for their cause.

Today, scientists know that some flame retardants escape from household products and settle in dust. That’s why toddlers, who play on the floor and put things in their mouths, generally have far higher levels of these chemicals in their bodies than their parents.

Blood levels of certain widely used flame retardants doubled in adults every two to five years between 1970 and 2004. More recent studies show levels haven’t declined in the U.S. even though some of the chemicals have been pulled from the market. A typical American baby is born with the highest recorded concentrations of flame retardants among infants in the world.

People might be willing to accept the health risks if the flame retardants packed into sofas and easy chairs worked as promised. But they don’t.

The chemical industry often points to a government study from the 1980s as proof that flame retardants save lives. But the study’s lead author, Vytenis Babrauskas, said in an interview that the industry has grossly distorted his findings and that the amount of retardants used in household furniture doesn’t work.

“The fire just laughs at it,” he said.

Other government scientists subsequently found that the flame retardants in household furniture don’t protect consumers from fire in any meaningful way.

The U.S. Environmental Protection Agency, meanwhile, has allowed generation after generation of flame retardants onto the market and into American homes without thoroughly assessing the health risks. The EPA even promoted one chemical mixture as a safe, eco-friendly flame retardant despite grave concerns from its own scientists about potential hazards to humans and wildlife.

Since the 1970s manufacturers have repeatedly withdrawn flame retardants amid health concerns. Some have been banned by a United Nations treaty that seeks to eliminate the worst chemicals in the world.

Chemtura Corp. and Albemarle Corp., the two biggest U.S. manufacturers of flame retardants, say their products are safe and effective, arguing that they have been extensively evaluated by government agencies here and in Europe.

“Flame retardants provide an essential tool to enable manufacturers of products to meet the fire safety codes and standards necessary to protect life and property in a modern world,” John Gustavsen, a Chemtura spokesman, said in a written statement.

His company, Gustavsen said, strongly disagrees with the main findings of the Tribune’s investigation.

Heimbach, the burn doctor, has regularly supported the industry’s position that flame retardants save lives. But he now acknowledges the stories he told lawmakers about victims were not always factual.

He told the Tribune his testimony in California was “an anecdotal story rather than anything which I would say was absolutely true under oath, because I wasn’t under oath.”

Heimbach, a retired Seattle doctor and former president of the American Burn Association, also said his anecdotes were not about different children but about the same infant. But records and interviews show that the baby Heimbach said he had in mind when testifying didn’t die as he described and that flame retardants were not a factor.

After the Tribune confronted chemical executives with Heimbach’s questionable testimony, he offered, through his lawyer, another explanation for why his stories didn’t add up: He intentionally changed the facts to protect patient privacy.

Yet the most crucial parts of his testimony — the cause of the fire and the lack of flame retardants — had nothing to do with privacy. Instead, they served to bolster the industry’s argument that chemical retardants save lives.

In the last quarter-century, worldwide demand for flame retardants has skyrocketed to 3.4 billion pounds in 2009 from 526 million pounds in 1983, according to market research from The Freedonia Group, which projects demand will reach 4.4 billion pounds by 2014.

As evidence of the health risks associated with these chemicals piled up, the industry mounted a misleading campaign to fuel demand.

There is no better example of these deceptive tactics than the Citizens for Fire Safety Institute, the industry front group that sponsored Heimbach and his vivid testimony about burned babies.

FEAR AND DECEPTION

In the website photo, five grinning children stand in front of a red brick fire station that could be on any corner in America. They hold a hand-drawn banner that says “fire safety” with a heart dotting the letter “i.”

Citizens for Fire Safety describes itself as a group of people with altruistic intentions: “a coalition of fire professionals, educators, community activists, burn centers, doctors, fire departments and industry leaders, united to ensure that our country is protected by the highest standards of fire safety.”

Heimbach summoned that image when he told lawmakers that the organization was “made up of many people like me who have no particular interest in the chemical companies: numerous fire departments, numerous firefighters and many, many burn docs.”

But public records demonstrate that Citizens for Fire Safety actually is a trade association for chemical companies. Its executive director, Grant Gillham, honed his political skills advising tobacco executives. And the group’s efforts to influence fire-safety policies are guided by a mission to “promote common business interests of members involved with the chemical manufacturing industry,” tax records show.

Its only sources of funding — about $17 million between 2008 and 2010 — are “membership dues and assessments” and the interest that money earns.

The group has only three members: Albemarle, ICL Industrial Products and Chemtura, according to records the organization filed with California lobbying regulators. Those three companies are the largest manufacturers of flame retardants and together control 40 percent of the world market for these chemicals, according to The Freedonia Group, a Cleveland-based research firm.

Citizens for Fire Safety has spent its money primarily on lobbying and political expenses, tax records show. Since federal law makes it nearly impossible for the EPA to ban toxic chemicals and Congress rarely steps in, state legislatures from Alaska to Vermont have become the sites of intense battles over flame retardants.

Many of the witnesses supporting flame retardants at these hearings were either paid directly by Citizens for Fire Safety or were members of groups that benefited financially from Citizens for Fire Safety’s donations, according to tax documents and other records.

At the same time, Citizens for Fire Safety has portrayed its opposition as misguided, wealthy environmentalists. But its opponents include a diverse group of public health advocates as well as firefighters who are alarmed by studies showing some flame retardants can make smoke from fires even more toxic.

Matt Vinci, president of the Professional Fire Fighters of Vermont, faced what he called “dirty tactics” when he successfully lobbied for his state to ban one flame retardant chemical in 2009.

Particularly offensive to Vinci were letters Citizens for Fire Safety sent to Vermont fire chiefs saying the ban would “present an additional hazard for those of us in the fire safety profession.” But the letter’s author wasn’t a firefighter; he was a California public relations consultant.

“Citizens for Fire Safety did everything they could to portray themselves as firefighters, as Vermont citizens for fire safety, when it really wasn’t Vermont citizens for fire safety at all,” Vinci said.

The group also has misrepresented itself in other ways. On its website, Citizens for Fire Safety said it had joined with the international firefighters’ association, the American Burn Association and a key federal agency “to conduct ongoing studies to ensure safe and effective fire prevention.”

Both of those organizations and the federal agency, however, said that simply is not true.

“They are lying,” said Jeff Zack, a spokesman for the International Association of Fire Fighters. “They aren’t working with us on anything.”

After inquiries from the Tribune, Citizens for Fire Safety deleted that passage from its website.

Gillham, the executive director, declined to comment. Albemarle, Chemtura and ICL Industrial Products also declined to answer specific questions about the group.

Albemarle Chief Sustainability Officer David Clary did say that his company has been transparent about its funding of Citizens for Fire Safety.

“We believe that this support for advocacy groups is critical to raise awareness of the importance of fire safety and give a voice to those who want to speak out on this important public issue,” Clary said in a written statement.

Citizens for Fire Safety is the latest in a string of industry groups that have sprung up on different continents in the last 15 years — casting doubt on health concerns, shooting down restrictions and working to expand the market for flame retardants in furniture and electronics.

For example, the Bromine Science and Environmental Forum, based in Brussels, may sound like a neutral scientific body. But it was founded and funded by four chemical manufacturers, including Albemarle, to influence the debate about flame retardants made with bromine.

Albemarle’s global director of product advocacy, Raymond Dawson, said in blunt testimony before Washington state lawmakers in 2007 that the forum is “a group dedicated to generating science in support of brominated flame retardants.”

An official from Burson-Marsteller, the global public relations firm that helps run the organization, said the bromine group is not misleading anyone because regulators, scientists and other stakeholders are well-aware it represents industry.

The PR firm also helps run the Alliance for Consumer Fire Safety in Europe, which is funded by a trade association of flame retardant manufacturers. The alliance’s director, Bob Graham, said the group’s aim is to improve fire-safety standards for upholstered furniture sold in Europe.

The group’s website taps into the public’s fear of fire, touting an “interactive burn test tool” that allows visitors to choose a European country and watch a sofa from that nation being torched.

Next to a photo of an easy chair fully engulfed in flames, four words stand out in large capital letters: “ARE YOU SITTING COMFORTABLY?”

‘IMAGINE A CHILD CRYING’

The amount of flame retardants in a typical American home isn’t measured in parts per billion or parts per million. It’s measured in ounces and pounds.

A large couch can have up to 2 pounds in its foam cushions. The chemicals also are inside some highchairs, diaper-changing pads and breast-feeding pillows. Recyclers turn chemically treated foam into the padding underneath carpets.

“When we’re eating organic, we’re avoiding very small amounts of pesticides,” said Arlene Blum, a California chemist who has fought to limit flame retardants in household products. “Then we sit on our couch that can contain a pound of chemicals that’s from the same family as banned pesticides like DDT.”

These chemicals are ubiquitous not because federal rules demand it. In fact, scientists at the U.S. Consumer Product Safety Commission have determined that the flame retardants in household furniture aren’t effective, and some pose unnecessary health risks.

The chemicals are widely used because of an obscure rule adopted by California regulators in 1975. Back then, a state chemist devised an easy-to-replicate burn test that didn’t require manufacturers to set furniture on fire, an expensive proposition.

The test calls for exposing raw foam to a candle-like flame for 12 seconds. The cheapest way to pass the test is to add flame retardants to the foam inside cushions.

But couches aren’t made of foam alone. In a real fire, the upholstery fabric, typically not treated with flame retardants, burns first, and the flames grow big enough that they overwhelm even fire-retardant foam, scientists at two federal agencies have found.

Nevertheless, in the decades since that rule went into effect, lawyers have regularly argued that their burn-victim clients would have been spared if only their sofas had been made with California foam. Faced with the specter of these lawsuits — and the logistical challenge of producing separate products just for California — many manufacturers began using flame retardant foam across their product lines.

As a result, California has become the most critical battleground in recent years for advocates trying to reduce the prevalence of these chemicals in American homes.

Citizens for Fire Safety has successfully fought back with a powerful, and surprising, tactic: making flame retardants a racial issue.

The group and witnesses with ties to it have argued that impoverished, minority children would burn to death if flame retardants were removed from household products.

In 2009, for instance, members of the California State Assembly were considering a bill that would have made it unnecessary to add flame retardants to many baby products by excluding them from the state’s flammability regulation.

Up to the microphone stepped Zyra McCloud, an African-American community activist from Inglewood, Calif.

McCloud was president of a community group that listed Citizens for Fire Safety as a sponsor on its website and included photos of McCloud with Gillham, the executive director. She did not disclose this connection to the assembly, nor was she asked.

In a news release, Citizens for Fire Safety already had quoted McCloud saying that minority children, who constitute a disproportionate share of fire deaths, would bear the brunt of the “ill-conceived and unsafe legislation.”

At the hearing, the committee chairwoman told both sides they were out of time for testimony, but McCloud pleaded with her to allow two elementary school students from her district to address lawmakers.

“We have spent all weekend long with the kids that have had family members and friends who have died in fires, and we are praying and appealing to you that you would at least allow the two boys to speak,” she said.

One of the boys, a 10-year-old, read from a statement.

“I just want you to imagine a child crying for help in a burning building, dying, when there was a person who only had to vote to save their life,” he said.

Citizens for Fire Safety prevailed. The bill later went down to defeat.

McCloud told the Tribune, “I’ve always been a person that’s fought against things that would hurt children.” She then asked for questions in writing but never answered them.

Nearly two years after that bill failed, one of the nation’s top burn surgeons would also invoke the image of a dead child before California lawmakers on behalf of Citizens for Fire Safety.

‘THIS IS HORRIBLE’

When Dr. David Heimbach walked into the California Senate committee hearing last year, the stakes had never been higher for flame retardant manufacturers.

Once again, senators were considering an overhaul of the state’s flammability regulation — one that advocates believed would dramatically reduce the amount of flame retardants in American homes.

The bill would allow manufacturers to choose the existing candle-like flame test or a new one based on a smoldering cigarette, a far more common source of fires than candles. Manufacturers could pass the new test by using resistant fabrics rather than adding toxic chemicals to the foam inside.

To maintain the status quo — and avoid a hit to the bottom line — chemical makers needed to stress that fires started by candles were a serious threat.

Heimbach, Citizens for Fire Safety’s star witness, did just that.

With Citizens for Fire Safety’s Gillham watching from the audience, Heimbach not only passionately described the fatal burns a 7-week-old Alaska patient received lying on a pillow that lacked flame retardants, he also blamed the 2010 blaze on a candle.

In fact, he specifically said the baby’s mother had placed a candle in the girl’s crib.

Heimbach had told similar stories before, the Tribune found. In 2009, he told a California State Assembly committee that he had treated a 9-week-old girl who died that spring after a candle beside her crib turned over. “We had to split open her fingers because they were so charred,” he testified.

In 2010, he told Alaska lawmakers about a 6-week-old girl from Washington state who died that year after a dog knocked a candle onto her crib, which did not have a flame retardant mattress.

Heimbach’s hospital in Seattle, Harborview Medical Center, declined to help the Tribune confirm his accounts. But records from the King County medical examiner’s office show that no child matching Heimbach’s descriptions has died in his hospital in the last 16 years.

The only infant who came close in terms of age and date of death was Nancy Garcia-Diaz, a 6-week-old who died in 2009 after a house fire in rural Washington.

In an interview, Heimbach said his anecdotes were all about the same baby — one who died at his hospital, though he didn’t know the child’s name. Contrary to his testimony, he said he had not taken care of the patient.

Told about Nancy, Heimbach said she was probably the baby he had in mind and emailed a Tribune reporter two photographs of a severely burned child, images that he said he had used in a presentation at a medical conference. Medical records and Nancy’s mother confirmed those pictures were indeed of Nancy.

But Nancy didn’t die in a fire caused by a candle, as Heimbach has repeatedly testified. Fire records obtained by the Tribune show the blaze was caused by an overloaded, overheated extension cord.

“There were no candles, no pets — just the misuse of extension cords,” said Mike Makela, an investigator for the Snohomish County fire marshal’s office.

In his testimony last year, Heimbach stated the baby was in a crib on a fire-retardant mattress and on a non-retardant pillow. The upper half of her body was burned, he said.

But public records show there was no crib — she was resting on a bed — and no pillow. And, Makela said, flame retardants played no role in the pattern of her burns.

Fire authorities, Heimbach said, “may know more about it than I do, but that was the information that I had.”

Heimbach said he couldn’t recall who gave him that information but that Citizens for Fire Safety did not help craft his statements. He said the group has paid for his travel to testify and for some of his time, though he would not give a dollar amount.

The details of his statements, he said, weren’t as important as the principle. “The principle is that fire retardants will retard fires and will prevent burns,” he said.

Later, Heimbach said through his attorney that federal rules prohibit him from disclosing information that would identify a patient. He said that when describing particular burn cases, he follows standard protocol under the rules by “de-identifying” patients — that is, changing or omitting identifying information to protect their privacy.

But in testimony at state hearings, Heimbach not only changed facts, he added new ones, such as candles starting deadly blazes and the lack of flame retardants — details that aided the chemical industry’s position.

Nancy’s mother, who asked that her name not be used, said she never granted Heimbach permission to use her daughter’s photograph.

“Nancy’s memory is sacred to us,” she said. “My daughter deserves respect. She lived such a short time and she suffered a lot. This is horrible.”

Heimbach was head of Harborview’s burn center for 25 years; he also was a professor of surgery at the University of Washington until his retirement last year. He estimated he might have saved “hundreds if not thousands” of lives. In 2009, the Dalai Lama presented Heimbach an award for his pioneering care of burn victims around the world.

“I’m a well-meaning guy,” Heimbach said. “I’m not in the pocket of industry.”

When Heimbach testified last spring in California on the bill that could have significantly reduced the use of flame retardants, he didn’t tell lawmakers he was altering facts about the burn victim. Only when asked by a senator did he reveal that Citizens for Fire Safety paid for his trip there.

When it came time to vote, the senators overwhelmingly sided with Heimbach and Citizens for Fire Safety, sticking with the furniture standard based on a candle-like flame.

Public health advocates had one last hope: Senators had seven days in which they could change their votes. As the advocates tried to persuade senators to reconsider, Citizens for Fire Safety put out a news alert that linked to a video called “Killer Couches!”

To the sounds of sinister music and crackling flames, a sofa made without flame retardants became an inferno. Then these words appeared: “Are You Sitting Comfortably?”

No senators changed their votes, and the bill was dead. The chemical companies had won again.

Tribune reporter Michael Hawthorne contributed to this report.

pcallahan@tribune.com

sroe@tribune.com

See the link below for additional information and videos

http://media.apps.chicagotribune.com/flames/index.html

TOBACCO’S CLOUT – Part two: ‘Our fire service friends’

Big Tobacco wins fire marshals as allies in flame retardant push

Cigarette-makers had man on the inside of key fire-safety group

By Patricia Callahan and Sam Roe, Chicago Tribune reporters
May 8, 2012

The problem facing cigarette manufacturers decades ago involved tragic deaths and bad publicity, but it had nothing to do with cancer. It had to do with house fires.

Smoldering cigarettes were sparking fires and killing people. And tobacco executives didn’t care for one obvious solution: create a “fire-safe” cigarette, one less likely to start a blaze.

The industry insisted it couldn’t make a fire-safe cigarette that would still appeal to smokers and instead promoted flame retardant furniture — shifting attention to the couches and chairs that were going up in flames.

But executives realized they lacked credibility, especially when burn victims and firefighters were pushing for changes to cigarettes.

So Big Tobacco launched an aggressive and cunning campaign to “neutralize” firefighting organizations and persuade these far more trusted groups to adopt tobacco’s cause as their own. The industry poured millions of dollars into the effort, doling out grants to fire groups and hiring consultants to court them.

These strategic investments endeared cigarette executives to groups they called their “fire service friends.”

“To give us clout, to give us power, to give us credibility, to give us leverage, to give us access where we don’t ordinarily have access ourselves — those are the kinds of things that we’re looking for,” a Philip Morris executive told his peers in a 1984 training session on this strategy.

The tobacco industry’s biggest prize? The National Association of State Fire Marshals, which represented the No. 1 fire officials in each state.

A former tobacco executive, Peter Sparber, helped organize the group, then steered its national agenda. He shaped its requests for federal rules requiring flame retardant furniture and fed the marshals tobacco’s arguments for why altering furniture was a more effective way to prevent fires than altering cigarettes.

For years, the tobacco industry paid Sparber for what the marshals mistakenly thought was volunteer work.

The Tribune discovered details about Big Tobacco’s secretive campaign buried among the 13 million documents cigarette executives made public after settling lawsuits that recouped the cost of treating sick smokers. These internal memos, speeches and strategic plans reveal the surprising and influential role of Big Tobacco in the buildup of toxic chemicals in American furniture.

This clever manipulation set the stage for a similar campaign of distortion and misdirection by the chemical industry that continues to this day.

Andrew McGuire, a burn survivor and MacArthur “genius grant” winner, said Sparber and the National Association of State Fire Marshals for years were his nemeses as he has pushed for fire-safe cigarettes, which would stop burning when not being smoked. McGuire came up against them again when he battled for reductions in the amount of flame retardant chemicals in Americans’ homes.

“He played them like a Stradivarius,” McGuire said of Sparber’s relationship with the fire marshals.

A founding member of the fire marshals group disputes that they were unduly influenced, but he said he regrets that the organization accepted tobacco’s money.

“There is no way you can explain to the public that taking money from the tobacco industry is a good thing,” said Tom Brace, who served as a marshal in Minnesota and Washington state. “And had I to do that over again, I would not do that.”

Brace and the fire marshals group often were at odds with colleagues in the firefighting community who worked to scale back the use of certain flame retardants after studies showed they can make smoke more toxic.

The fire marshals organization continued promoting flame retardant products even after it was clear that the chemicals inside were escaping, settling in dust and winding up in the bodies of babies and adults worldwide.

The marshals continued even after flame retardants were linked to cancer, neurological deficits, developmental problems and impaired fertility.

And they continued even after government scientists showed that flame retardants in household furniture were not protecting Americans from fire in any meaningful way.

Wooing the marshals

With the top executives of the largest U.S. cigarette companies gathered in a New York ballroom, Charles Powers rose to report that their trade group’s multimillion-dollar investment in the firefighting community was paying off nicely.

It was October 1989, and the CEOs behind Marlboro, Camel and other major brands were in a closed-door meeting of the executive committee of the Tobacco Institute, the trade group that fought legislation that could hurt their business.

Powers noted that many fire officials who once were hostile were endorsing industry positions in key federal and state legislative battles over fire-safe cigarettes. The strategy by the Tobacco Institute of winning over these officials, including some state fire marshals, with grants and schmoozing was working.

“Though our assistance is ‘no strings attached’ for everyone, it is no accident that the fire service officials most interested in our educational materials are also the fire service leaders whom we have approached for endorsements,” said Powers, a top executive at the Tobacco Institute.

He boasted: “Many of our former adversaries in the fire service defend us, support us and carry forth our federal legislation as their own.”

Much of that success can be attributed to the fact that Big Tobacco had planted an inside man within the firefighting community.

A former Tobacco Institute vice president, Peter Sparber had spent years at the trade group doling out money to firefighting groups. He left to open his own lobbying and public affairs firm in the late 1980s but retained the Tobacco Institute as a major client.

This arm’s-length relationship — working for Big Tobacco but having a business card that said “Sparber and Associates Inc.” — allowed him to infiltrate an organization of public officials that became what the Tobacco Institute later called “the most politically potent group” in the firefighting community: the nation’s state fire marshals.

These taxpayer-funded employees, typically appointed by governors, had a low profile nationally until Sparber came along. In 1989, Sparber helped organize the National Association of State Fire Marshals and volunteered to be the group’s legislative consultant. The fire marshals put him on their executive board.

Sparber became so crucial to the fire marshals that they listed him on their association letterhead and for more than a decade shared a Washington office with him.

One of the marshals’ first official acts was to endorse a tobacco-backed federal bill that called for yet another study of fire-safe cigarettes rather than a competing bill that would have quickly required cigarettes to change.

Like his tobacco industry patrons, Sparber worked to prevent a mandate for fire-safe cigarettes by shifting the focus to furniture.

For years, Sparber promoted an obscure California state rule on furniture flammability, one that manufacturers met by adding flame retardant chemicals to the foam in sofas and easy chairs.

California regulators had enacted the rule in 1975 out of frustration that too many residents were dying in fires caused by cigarettes. State and federal lawmakers had tried unsuccessfully since the 1920s to enact fire-safe cigarette requirements, so California regulators instead sought to fireproof the world around the cigarette.

With Sparber’s help, the fire marshals in 1992 sought federal rules for flame retardant furniture, and Sparber went on to represent the marshals in years of meetings with the U.S. Consumer Product Safety Commission. His expense reports show that for several years he was billing the Tobacco Institute $200 an hour for his work with the marshals, including time he spent on the marshals’ petition for flame retardant furniture.

Sparber reported to the institute on the fire marshals’ key activities and even passed along their internal documents. Tobacco Institute President Samuel Chilcote Jr., in turn, sent detailed memos to the CEOs of cigarette companies about the marshals’ activities.

Chilcote declined to comment to the Tribune, saying he couldn’t recall what happened so long ago.

Brace, a founder of the fire marshals group, said he knew Sparber was a former Tobacco Institute executive. But Brace said he didn’t know in the association’s early days that the institute was paying Sparber for his work with the marshals and didn’t know that Sparber funneled so many of the marshals’ internal documents to the cigarette industry.

Nevertheless, Brace said the marshals made their own decisions.

“The inference that the state fire marshals sitting around the table are easily led by this Svengali — there were arguments back and forth of what we should get involved in,” Brace said in an interview. “We had some hot debates. But the characterization that Sparber led us out of the wilderness, I don’t see it.”

But records in tobacco executives’ files show that Sparber helped set the fire marshals’ agenda, suggesting who should speak at a key conference, which consultants they should retain and why they should oppose aggressive fire-safe cigarette requirements.

He also assisted the fire marshals with fundraising, nudging tobacco colleagues to contribute to the group.

Too close for comfort

Assisting Sparber was an old fan: Karen Deppa.

Deppa had solidified Sparber’s reputation in the world of spin when, in a previous job as a journalist, she penned a glowing profile of Sparber for a magazine aimed at trade association executives. The story described him as a master of crisis management whom others could emulate, noting the deft way he had positioned smoking as a fundamental freedom and cast doubt on studies documenting the health hazards of smoking.

“I go home to my family every night, and not once have I felt uncomfortable about facing them over anything I’ve done at work,” Sparber said in that article.

Within a year of the publication, the Tobacco Institute hired Deppa and made her the coordinator of its fire program. Records show she frequently signed off on Sparber’s hourly billings for his work with the marshals.

Deppa ensured the Tobacco Institute pampered the marshals — faced with lean state budgets — with perks at the group’s conferences, including bottles of wine, a hospitality suite and free mountain bike rentals, records show. She pressed the institute to fund a media-training seminar for the marshals, suggesting this would make them more confident speakers as they publicly discussed fire-safe cigarettes and other issues.

The fire marshals wound up using tobacco’s talking points in the industry’s protracted delay game.

When leaders of the marshals association addressed federal regulators, they would say they supported the concept of a national fire-safe cigarette requirement. But in the next breath, the marshals would nitpick the test methods federal scientists created to determine which cigarettes were less likely to cause fires.

Tobacco executives loathed those tests. Publicly, they argued that the tests failed to replicate “real world” conditions. Privately, they feared the tests would pave the way for laws that would force them to alter cigarettes — products that made them billions of dollars each year — in ways that their customers wouldn’t like, records show. Some prototypes had an unpleasant taste or were difficult to smoke.

An internal R.J. Reynolds Tobacco Co. report noted that the lack of a standard test method had served to delay the adoption of fire-safe cigarette bills in 12 states.

The marshals’ criticisms of the details of the tests were straight from Big Tobacco’s playbook. This wasn’t a coincidence. Questioned by a government scientist at a meeting of the federal panel crafting the tests, one marshal acknowledged that Sparber had briefed him on the issues, records show.

“They learned very quickly from their puppet masters how to craft the arguments to seem reasonable but cause delay,” recalled McGuire, the burn survivor, who was a member of the panel and was at that meeting.

David Sutton, a spokesman for Philip Morris USA, rejected the notion that his company and the fire marshals worked together to delay fire-safe cigarette rules. For more than a decade, he said, the company worked hard to develop marketable cigarettes that were more likely to extinguish on their own.

Philip Morris collaborated with the marshals on flame retardant furniture standards in the early 1990s, he said, because the company believed those might present “a potentially more effective alternative for improved fire safety.”

By 1993, records show, the fire marshals were so vehemently opposed to fire-safe cigarette test proposals — and so financially and philosophically connected to the cigarette industry — that a top Philip Morris lobbyist told the Tobacco Institute she feared that the marshals had actually become a liability. Records show she told colleagues she thought the National Association of State Fire Marshals was “tainted.”

The lobbyist worried that “the relationship of the industry — especially Philip Morris — to the National Association of State Fire Marshals (NASFM) may eventually be disclosed publicly.” She suggested to the Tobacco Institute that the fire marshals stop discussing fire-safe cigarettes and focus solely on furniture flammability standards.

But the industry didn’t sever ties, in part because other cigarette executives thought they needed the marshals to counter fire-service groups that were pushing for fire-safe cigarette laws, records show.

A key prong in R.J. Reynolds’ 1996 strategic plan to fight these laws was the marshals’ petition to the Consumer Product Safety Commission for flame retardant furniture rules. A handwritten note on the first page directs an R.J. Reynolds employee to file the plan under “Fire Safe Sparber.”

The plan used italics to hammer home the urgency of focusing on the furniture fueling fires, not the cigarettes igniting them: “In 1996, fire officials must keep the pressure on the Commission to focus on the fuels rather than ignition sources.”

Playing ‘hardball’

The fire marshals’ actions helped Big Tobacco fend off fire-safe requirements for years. But the delays couldn’t go on forever.

The Tobacco Institute shut down in 1999, a requirement of the multibillion-dollar court settlement between the industry and state attorneys general. Not long after that, states succeeded in passing rules requiring fire-safe cigarettes, so tobacco no longer had an incentive to promote flame retardant furniture.

But by then Sparber had found new clients with problems of their own: chemical manufacturers.

With each passing year, health concerns were growing as the most commonly used types of flame retardants were discovered in human breast milk and blood.

As Sparber worked to preserve and even expand the market for flame retardants, the fire marshals were again at his side. So was Deppa, whom he had hired from the Tobacco Institute.

So intertwined were Sparber, the chemical companies and the fire marshals that even Sparber couldn’t always differentiate where the agendas diverged.

For instance, one of Sparber’s clients as a lobbyist was the Bromine Science and Environmental Forum, an international trade group representing large manufacturers of flame retardants. Sparber revealed to federal regulators in 1999 that although the forum was paying his company’s fees, the chemical group’s goals for fire prevention were so aligned with those of the fire marshals association that he often lobbied for both groups on the same matters.

Chemtura Corp.,Albemarle Corp.and ICL Industrial Products — the three largest companies that fund the bromine forum — declined to answer questions about their relationships with Sparber or the fire marshals. Chemtura and Albemarle said their flame retardants are safe and effectively protect people and property from fires.

Brace, the former marshal, confirmed that his association became “heavily involved” with the flame retardant trade group and supported its agenda. He said he worked with the forum because of his desire to save lives, and he was leery of studies that linked the chemicals to health problems.

The bromine group, Brace said, paid for him to go to Japan, Korea and Taiwan, where he urged electronics manufacturers to add flame retardants to the plastic exteriors of computer monitors and televisions. The marshals later pushed for worldwide standards requiring that the plastic casings of electronics resist a candle flame and posted Internet videos comparing name-brand computer monitors that went up in flames with those that didn’t.

John Dean, the fire marshals’ president from 2006 to 2008, said that during his time the marshals were not being swayed by chemical companies and did not focus solely on flame retardants. “The fire marshals were concerned about preventing fires, and we didn’t really care how they did it,” said Dean, a retired state fire marshal from Maine.

But the marshals did press for national furniture flammability rules that would have increased the use of flame retardant foam in the U.S., even though federal scientists had concluded that this type of chemically treated foam didn’t provide any meaningful protection in fires.

To sway legislators and opponents, the marshals and Sparber characterized couches and easy chairs as dangers to society, sometimes referring to the foam inside cushions as “solid gasoline.”

While Sparber was a registered lobbyist for Chemtura and its predecessor, Great Lakes Chemical Corp., the fire marshals asked federal regulators to require warning labels on furniture made with non-fire-retardant foam and sought a “hazardous material” designation for this type of foam.

In 2007, Sparber emailed executives at Chemtura and Albemarle about his efforts to get furniture stores declared “hazardous occupancies,” a classification usually reserved for locations handling gasoline and other highly combustible materials.

Such a designation, Sparber wrote, “threatens to shut down any number of retailers,” limit the number of sofas they could store or force them to install extensive sprinkler systems.

“Literally,” he wrote, “a single sectional couch might exceed the limit.”

The goal, Sparber wrote, was to make furniture manufacturers and retailers fear these “obviously draconian consequences” and thereby support strict flammability standards or face the wrath of code enforcement officials.

“This is hardball of the first order,” Sparber wrote.

While these rules weren’t adopted, the intimidating message hit a nerve with the industries Sparber threatened. Joseph Gerard, a retired furniture industry lobbyist, said he recalls Sparber sending him an inches-thick binder filled with copies of the same Associated Press story clipped from newspapers across the country. The story blamed the death of a South Carolina teenager on sofas that lacked flame retardants and quoted a fire marshal about the need for the chemicals.

Gerard said of Sparber: “His way of operating was so offensive, it just tore at me.”

To the fire marshals, though, Sparber was a hero. The National Association of State Fire Marshals gave him its Hall of Fame award in 2008.

Sparber and Deppa declined to comment for this story.

Jim Narva, the fire marshals’ current executive director, said Sparber has not represented the group for “a number of years” and that he took over Sparber’s Washington office in 2008 or 2009.

“It’s history,” Narva said.

The marshals’ policy statement on flame retardants, which hasn’t been updated since 2008, says products that exist to fight fires should not be banned unless there is “significant evidence” that they cause harm or until other methods of fire protection are found to replace them.

Narva, who declined to answer detailed questions, said the fire marshals are not currently involved with flame retardant issues.

But the marshals’ industry ties remain strong.

Deppa left Sparber and Associates in 2008 and, according to the marshals’ website, became the group’s “liaison to US government agencies and their staffs.”

The marshals just last year helped defeat a crucial bill in California that would have reduced flame retardants in products nationwide. The association’s president at the time wrote a letter opposing the legislation. A lobbyist for the Citizens for Fire Safety Institute, a front group for the largest makers of flame retardants, read excerpts of the letter at the hearing where the bill was voted down.

And who remains a financial sponsor of the fire marshals, with its logo on the group’s home page?

Chemtura, one of the world’s largest producers of flame retardants.

Tribune reporter Michael Hawthorne contributed to this report.

pcallahan@tribune.com

sroe@tribune.com

http://www.chicagotribune.com/news/watchdog/flames/ct-met-flames-tobacco-20120508,0,6090419,full.story

DISTORTING SCIENCE

PART THREE: ‘Flat-out deceptive’

http://www.chicagotribune.com/news/watchdog/flames/ct-met-flames-science-20120509,0,2480120.story

Distorting science

Makers of flame retardants manipulate research findings to back their products, downplay health risks

By Sam Roe and Patricia Callahan, Chicago Tribune reporters
May 9, 2012

Twenty-five years ago, scientists gathered in a cramped government laboratory and set fire to specially designed chairs, TVs and electrical cables packed with flame retardants. For the next half-hour, they carefully measured how much the chemicals slowed the blaze.

It was one of the largest studies of its kind, and the chemical industry seized upon it, claiming the results showed that flame retardants gave people a 15-fold increase in time to escape fires.

Manufacturers of flame retardants would repeatedly point to this government study as key proof that these toxic chemicals — embedded in many common household items — prevented residential fires and saved lives.

But the study’s lead author, Vytenis Babrauskas, told the Tribune that industry officials have “grossly distorted” the findings of his research, which was not based on real-world conditions. The small amounts of flame retardants in typical home furnishings, he said, offer little to no fire protection.

“Industry has used this study in ways that are improper and untruthful,” he said.

The misuse of Babrauskas’ work is but one example of how the chemical industry has manipulated scientific findings to promote the widespread use of flame retardants and downplay the health risks, a Tribune investigation shows. The industry has twisted research results, ignored findings that run counter to its aims and passed off biased, industry-funded reports as rigorous science.

As a result, the chemical industry successfully distorted the basic knowledge about toxic chemicals that are used in consumer products and linked to serious health problems, including cancer, developmental problems, neurological deficits and impaired fertility.

Industry has disseminated misleading research findings so frequently that they essentially have been adopted as fact. They have been cited by consultants, think tanks, regulators and Wikipedia, and have shaped the worldwide debate about the safety of flame retardants.

One series of studies financed by the chemical industry concluded that flame retardants prevent deadly fires, reduce pollutants and save society millions of dollars.

The main basis for these broad claims? A report so obscure it is available only in Swedish.

When the Tribune obtained a copy and translated it, the report revealed that many of industry’s wide-ranging claims can be traced to information regarding just eight TV fires in western Stockholm more than 15 years ago.

Although industries often try to spin scientific findings on the safety and effectiveness of their products, the tactics employed by flame retardant manufacturers stand out.

Tom Muir, a Canadian government research analyst for 30 years, called the broad claims based on the eight Stockholm TV fires “the worst example I have ever seen of deliberate misinformation and distortion.”

The American Chemistry Council, the leading trade group for the industry, said flame retardants are safe products that help protect life and property. “ACC’s work is grounded in scientific evidence, as we believe regulatory decisions related to chemistry must be evaluated on a scientific basis,” the trade group said in a written statement.

But when the Tribune asked the trade group to provide research that showed flame retardants are effective, the council initially provided only one study — the one Babrauskas wrote and now says is being distorted by industry.

Later, in response to additional questions from the newspaper, the trade group highlighted a different study as evidence that flame retardants work well: research based largely on the obscure Swedish report.

In reviewing key scientific studies and analyses behind the chemical industry’s most common arguments, the Tribune identified flaws so basic they violate central tenets of science.

‘Bogus’ conclusions

When Babrauskas and his team of scientists began their pioneering research in 1987, it was well-established that flame retardants slowed fires — at least when massive amounts were packed into products.

Less clear was what that meant in terms of precise gains in fire safety. Seeking answers, the chemical industry commissioned Babrauskas’ team at the National Bureau of Standards to conduct one of the first large-scale studies on the effectiveness of flame retardants.

The industry, Babrauskas said, wanted to know what would happen if the most potent and expensive chemicals were embedded in common items, such as TV cabinets and upholstered chairs. The industry picked out the flame retardants to be used, and Babrauskas’ team began custom-building the household items to be tested.

Working out of a yellow-brick laboratory with a large chimney, the researchers set fire to each item and then, in what Babrauskas called the “grand finale,” ignited a room full of samples containing large amounts of retardants and a room of items containing none. Among the conclusions: The room of flame retardant samples would provide people 15 times more escape time than the other room.

The results weren’t surprising. More noteworthy was the way industry misrepresented the results.

For example, the Bromine Science and Environmental Forum has regularly cited the 15-fold increase in escape time to argue that the flame retardants in everyday household products, such as TVs, save lives. “This should allow sufficient time for the fire brigade to reach your place before it is too late,” states the website of the forum, a Brussels-based industry group that is funded by the largest makers of flame retardants.

Babrauskas calls such claims “totally bogus” because the amounts of flame retardants in the burned samples in his tests were so much greater than what is found in typical consumer items.

“Where you would see them is in the aviation industry, NASA, naval facilities — the market where there is no sensitivity to dollar costs,” he said.

In fact, as Babrauskas explicitly noted in his study, research shows that the flame retardants in household furnishings such as sofas and chairs do not slow fire.

Many couches, love seats and chairs sold nationwide contain flame retardants to comply with a California flammability rule. But studies by the U.S. Consumer Product Safety Commission have concluded that this standard provides no meaningful protection from deadly fires.

The standard requires that raw foam withstand a candle-like flame for 12 seconds. But, Babrauskas said, upholstered furniture is covered with fabric, and if the cover ignites, the flames from the fabric quickly grow larger than that of a candle and overwhelm even flame retardant foam.

“The fire just laughs at it,” Babrauskas said.

The bottom line: Household furniture often contains enough chemicals to pose health threats but not enough to stem fires — “the worst of both possible worlds,” he said.

Babrauskas, who spent 16 years as a fire scientist at the National Bureau of Standards, now known as the National Institute of Standards and Technology, said he didn’t know the chemical industry was misrepresenting his study until two years ago when a scientist at the Lawrence Livermore National Laboratory in California contacted him. Babrauskas addressed the distortion in a paper he presented last year at an international conference, but the industry continues to misquote his work.

In its written statement, the chemistry council said the group has not mischaracterized Babrauskas’ study, saying the group has stated the research shows flame retardants “can provide” a 15-fold increase in escape time.

Babrauskas, now a consultant, said the industry is being “flat-out deceptive” and should stop misrepresenting his work in order to sell more flame retardants. “I don’t want to be part of anything that willfully and needlessly poisons the planet,” he said.

Tiny study, big claims

The report written in Swedish is so obscure you won’t find it online or among the millions of papers listed in government and industry databases. The American Chemistry Council says it doesn’t have a copy. Even the chemicals’ most vocal critics say they have never seen one.

Yet the paper about electrical fires in Sweden has had significant influence, thanks to the chemical industry’s manipulation of its findings.

The Tribune obtained a copy of the study from the only library in the world believed to have one, the National Library of Sweden, and had it translated. The 50-page report, written by a Swedish federal board, estimated the total number of electrical fires in Sweden by analyzing the causes of all fires in and around western Stockholm in 1995 and 1996.

The report’s main conclusion — that electrical fires in Sweden were less common than previously thought — was relatively insignificant. But a chemical industry team zeroed in on a tiny portion of the report and used it to manufacture several flimsy arguments for why flame retardants are good for society.

At the time the Swedish report was published, in 1997, environmentalists in Europe were raising concerns about flame retardants in TVs and other electronics. The chemical industry began searching for evidence that the benefits of flame retardants in those products outweighed any risks.

Leading the search were three people with close industry ties: an executive with flame retardant maker Albemarle Corp.; a public relations specialist with a unit of Burson-Marsteller, a global PR firm; and Margaret Simonson, a fire scientist at a leading research institute in Sweden.

The three were collecting statistics on electrical fires when some data in the Swedish study caught their eye: Western Stockholm, with 265,000 residents, experienced 32 electrical fires in a two-year span. Of those 32 fires, eight — or 25 percent — were caused by TVs.

A basic principle of science is that broad conclusions should not be based on small or unrepresentative samples. Flip a coin five times and it might land on heads each time. But you couldn’t then conclude that 500 coin flips would always come up heads.

Yet the three industry researchers used the 25 percent figure to estimate that Europe as a whole — a region of roughly 500 million people — had experienced 165 TV fires per million sets annually.

That rate, the researchers wrote, was far higher than the U.S. rate, which they put at five TV fires per million sets. And because the outer plastic casings of televisions in the U.S. typically contained flame retardants, while European sets did not, the researchers concluded that the “dramatic difference” in TV fire rates was due to the chemicals.

When the researchers published their figures in 2000 in a peer-reviewed journal, one of the authors listed was the PR specialist.

Simonson, the fire scientist, went on to write several additional papers — all funded by the flame retardant industry — that also relied on the eight fires as support for her broad conclusions.

For example, in a 2002 study that looked at the environmental impact of TV sets, Simonson concluded that sets with flame retardants actually are responsible for lower emissions of certain hazardous pollutants over their lifetimes than TVs without retardants. This is primarily because, she wrote, TVs with retardants are involved in fewer and smaller fires, so they produce less smoke.

Industry repeatedly has pointed to this study when addressing environmental concerns about flame retardants.

Simonson’s figures have been quoted far and wide. European regulators credited her statistics for prodding some international TV manufacturers to add flame retardants to sets sold in Europe.

One of the few to question Simonson’s studies has been Tom Muir, a retired analyst for Canada’s environmental protection agency.

He translated bits of the obscure Swedish report but said he couldn’t entirely understand Simonson’s methodology. In an interview with the Tribune, Muir said her studies appeared to be “an elaborate, manufactured platform of assumption strings and assertions and extrapolations.”

When the Tribune provided Muir with a complete translation of the Swedish study as well as Simonson’s responses to the newspaper’s questions about her methods, Muir was even more critical.

“It’s worse than I thought,” he said, noting that Simonson repeatedly estimated crucial statistics when solid data did not exist. “She’s just making these numbers up.”

Also critical of Simonson’s calculations is the author of the Swedish study that Simonson relied on in her work.

Ingvar Enqvist said in an interview that he did not know Simonson and the chemical industry were relying on the eight TV fires mentioned in his report as the basis for sweeping claims about the benefits of flame retardants, a fact he called “a little peculiar.” He also said Simonson shouldn’t extrapolate the eight fires to all of Europe, given the vast differences among the countries.

Simonson, who now uses her maiden name and goes by Margaret Simonson McNamee, is a research manager at the SP Technical Research Institute of Sweden. She denied Muir’s accusation of fabricating numbers but acknowledged using many statistical extrapolations and assumptions because, she said, solid data were scarce.

“We certainly did the best that we could given the data that we had available,” she said. She added that a British study had found similar TV fire rates in various European countries, so she thought it was fair to extrapolate the blazes in Sweden to all of Europe.

Simonson emphasized that her methods were transparent, allowing critics to redo her studies with different numbers if they like. “Part of the scientific process is having a dialogue and not necessarily being in agreement with your peers,” she said.

Besides receiving industry money for her research, Simonson chairs the science advisory committee of the National Association of State Fire Marshals, a group of American public officials that has worked closely with the chemical industry to push for wider use of flame retardant products.

But Simonson said she has never skewed findings to suit industry needs. “Marketing material is something that they produce themselves,” she said. “Our research was independent research.”

Muir disagrees. “She’s never erring on the other side,” he said. “Her numbers are always pointing in the same direction — in industry’s favor.”

‘Industry loves him’

When chemicals receive bad publicity, industry has a go-to person: Dennis Paustenbach.

A veteran toxicologist and industrial hygienist, he has sided with industry on some of the most controversial health issues. Working for tobacco industry lawyers, Paustenbach disputed federal regulators’ conclusion that secondhand smoking causes lung cancer in adults. His industry-supported work was used to cast doubt on the risks of some occupational exposures to benzene and asbestos, two carcinogens.

“Industry loves him,” said Peter Infante, a former senior administrator with the U.S. Occupational Safety and Health Administration. “They know what answer they are going to get. Nothing is ever harmful.”

For the makers of flame retardants, Paustenbach helped interpret data about whether a widely used retardant posed a risk to children.

In 2002, concerns had been growing about a flame retardant known as deca that was being added to TVs and other electronics. The U.S. Environmental Protection Agency wanted more information about possible health risks to children, and chemical manufacturers volunteered to collect data and present them to an EPA-sponsored panel of industry, government and university researchers.

For help, the chemical-makers hired Exponent Inc., a California-based scientific consulting firm where Paustenbach served as vice president. After analyzing various ways children might be exposed to deca, including inhaling dust and chewing on consumer products, Paustenbach’s company wrote a 123-page report concluding the chemical posed little risk.

But its conclusions had a weak foundation: They were based to a large degree on a study of serum samples collected from just 12 adult blood donors in Illinois in 1988. Again, the chemical industry used a small sample to reach a broad conclusion.

In the Illinois blood study, researchers from the Centers for Disease Control and Prevention and Stockholm University found that five of the 12 serum samples had detectable amounts of deca. But when Paustenbach’s firm wrote up its report for the chemical industry, it flipped the findings around, emphasizing the seven samples where none of the chemical was detected.

“Given that the majority of serum samples tested had non-detectable levels of (deca), it is most likely that the majority of the U.S. population has very low, if not zero, exposure,” the report states.

The industry’s report also stated — contrary to the conclusion of the Illinois blood donor study — that no further evaluation of the flame retardant was warranted.

When the EPA panel of researchers reviewed the industry report, many members objected. They said the risk to the nation’s children should not lean so heavily on just 12 blood samples, let alone samples from adults, who tend to be less vulnerable to chemical exposure. Some members also noted the samples were collected in 1988, when levels of deca in the environment might have been lower.

Industry officials “were trying to pull a fast one,” recalled panel member Ruthann Rudel, a toxicologist at the Silent Spring Institute, an environmental research organization.

Paustenbach and five others went on to write up the report for a peer-reviewed journal, which can lend the results of a study more credibility.

Their paper was published in the Journal of Children’s Health — a year-old publication edited by Paustenbach.

In an interview, Paustenbach said it was appropriate to publish the report in a journal that he edited. He also defended the report’s use of the small sample of Illinois blood donors to cast doubt on the health risks of deca. “We did the best job we could with the available data,” he said.

Paustenbach is now president and founder of ChemRisk, a San Francisco-based consulting firm, and an adjunct professor of toxicology at the University of Michigan. Regarding criticism of his work for industry on controversial topics, he said: “It’s unfortunate there is such polarization in the environmental sciences on views on chemicals.”

In 2009, the three largest manufacturers of deca reached an agreement with the EPA to phase out sales of the chemical by the end of next year.

The journal that Paustenbach edited folded a few months after the questionable paper was published. Paustenbach said it closed because of competitive pressures.

It was in existence less than two years.

sroe@tribune.com

pcallahan@tribune.com

http://www.chicagotribune.com/news/watchdog/flames/ct-met-flames-science-20120509,0,5238451,full.story

TOXIC ROULETTE
PART FOUR: ‘Why do we not learn?’
http://www.chicagotribune.com/news/watchdog/flames/ct-met-flames-regulators-20120510,0,4262292.story

Toxic roulette

Firemaster 550, touted as safe, is the latest in a long line of flame retardants allowed onto the market without thorough study of health risks

By Michael Hawthorne, Chicago Tribune reporter
May 10, 2012

By the early 2000s, the flame retardant known as penta had become a villain.

Packed by the pound into couches and other furniture, the chemical was turning up in the blood of babies and in breast milk around the world. The European Union voted to ban penta after researchers linked it to developmental and neurological problems in children, and manufacturers pulled it from the market.

But the only U.S. company that made penta soon introduced a replacement, hailing it as the beginning of an eco-friendly era for flame retardants.

The new product even had a heroic name: Firemaster 550.

TheU.S. Environmental Protection Agency, whose mission is to safeguard America’s health and environment, praised the withdrawal of penta as a “responsible action” and promised that the new flame retardant had none of the problems of the old one. Unlike penta, Firemaster 550 would neither stick around in the environment nor build up in people and wildlife, a top EPA official declared in a 2003 news release.

Not everyone at the EPA believed that rosy public assessment. Documents obtained by the Tribune show that scientists within the agency were deeply skeptical about the safety of Firemaster 550, predicting that its chemical ingredients would escape into the environment and break down into byproducts that would pose lasting health hazards.

Behind the scenes, agency officials asked the manufacturer to conduct basic health studies, citing the same concerns that forced penta off the market.

Today, in sharp contrast to the promises of industry and government, chemicals in the flame retardant are being found everywhere from house dust in Boston to the air in Chicago. There also are signs the chemicals are building up in wildlife, prompting concern that Firemaster 550 or its byproducts could be accumulating in people.

The manufacturer’s own health studies, obtained by the Tribune, add to that troubling picture. They found that exposing rats to high doses of Firemaster 550 can lower birth weight, alter female genitalia and cause skeletal malformations such as fused ribs and vertebrae.

The history of Firemaster 550, pieced together through records obtained under the Freedom of Information Act, highlights how EPA officials have allowed generation after generation of flame retardants onto the market without thoroughly assessing health risks.

The previously unreleased documents also show how the nation’s chemical safety law, the 1976 Toxic Substances Control Act, gives the government little power to assess or limit dangers from the scores of chemicals added to furniture, electronics, toys, cosmetics and household products.

At a time when consumers clamor for more information about their exposure to toxic substances, the chemical safety law allows manufacturers to sell products without proving they are safe and to treat the formulas as trade secrets. Once health effects are documented, the law makes it almost impossible for the EPA to ban chemicals.

A growing list of critics — including the nation’s leading group of pediatricians and the Government Accountability Office, the investigative arm of Congress — are calling for a sweeping overhaul of the law. Some compare the situation to Whac-A-Mole, the carnival game where plastic moles keep popping out of holes even after a player smacks one down.

“By the time the scientific community catches up to one chemical, industry moves on to another and they go back to their playbook of delay and denial,” said Deborah Rice, a former EPA toxicologist who works for the Maine Center for Disease Control and Prevention.

Chemtura Corp., the Philadelphia-based company that makes Firemaster 550, said in a statement that the flame retardant is safe for use in polyurethane foam, the kind often used in furniture. The company also said the studies that found Firemaster 550’s chemical ingredients in homes and wildlife don’t prove that those compounds came from its product.

Introducing Firemaster 550 “was an early example of our strategy of Greener Innovation and the success it could have, even under significant EPA scrutiny,” the company said.

Nevertheless, the EPA is now concerned enough that in February it targeted two of Firemaster 550’s key ingredients for a “high priority” review, citing potential health hazards and widespread exposure from household products.

“We didn’t think it would bioaccumulate, but it turns out that prediction isn’t borne out by reality,” Jim Jones, the EPA’s top chemical safety official, said in an interview. “We want to make sure we understand it and that nothing bad is going to happen.”

Solving a mystery

When Firemaster 550 replaced penta, its chemical makeup was a mystery to all but the manufacturer and a select group of EPA employees who were sworn to secrecy. That made it difficult for outside scientists to identify its ingredients in the environment and determine if they are harmful.

Not until two young, independent chemists revealed the formula of Firemaster 550 did it become clear how far the flame retardant had spread in just a few years’ time.

One of the chemists, Duke University researcher Heather Stapleton, was among the first scientists to figure out that most human exposure to flame retardants comes from ingesting surprisingly large amounts of contaminated household dust, rather than from people’s diet or what they absorb through their skin.

Young children are exposed to significantly higher levels than adults, the EPA has since concluded, primarily because they spend so much time playing on the floor.

Stapleton’s interest in the chemicals started during graduate school in the late 1990s, when she was sent to Lake Michigan to monitor water pollution. Her discoveries in the Great Lakes helped document how penta and related flame retardants were spreading around the world, just like the banned pollutants DDT and PCBs.

She knew that many flame retardants in the U.S. are made with bromine or chlorine, chemicals known as halogens that take the place of oxygen and slow the combustive reaction that creates and spreads fire.

But other researchers have found that the way flame retardants are used in household furniture doesn’t protect people from fire in any meaningful way. And because of their chemistry, some of the most popular flame retardants spread easily and widely, persist in the environment and build up in the food chain.

In 2006, Stapleton discovered two mystery chemicals with high levels of bromine while analyzing dust samples from homes in Boston. The chemical structures didn’t show up in standard databases.

Around the same time, Susan Klosterhaus, a friend of Stapleton’s, got a job studying environmental contamination in San Francisco Bay. Mindful that Californians have some of the world’s highest recorded levels of flame retardants in their bodies, Klosterhaus wanted to know if Firemaster 550, the penta substitute promoted by the EPA, was showing up in the bay.

Like others at the time, Klosterhaus had no way to test for it because its formula was secret.

To solve the puzzle, she did two things: She sent Stapleton a small piece of foam from her new couch, and she called Chemtura to ask for a sample of Firemaster 550. To her surprise, the company sent a half-liter bottle containing an oily mixture the same color and thickness as maple syrup.

Stapleton analyzed the substance and confirmed the two chemists’ suspicions. The foam from the couch and the Boston dust samples both contained ingredients of Firemaster 550.

The scientists had identified a new pollutant. Without more study, though, there was no way to determine if it was dangerous.

“We end up finding a chemical mixture that’s produced in large volumes, yet there was next to nothing available in the public scientific literature about whether or not it might be harmful,” Klosterhaus said.

In May 2010, at a conference where Stapleton was speaking to foam manufacturers about her dust studies, Chemtura distributed a letter to the audience. It acknowledged that one of the company’s own animal studies had shown that Firemaster 550 had “some effects” on prenatal development.

Even so, the letter said, there was nothing to worry about because the company had found that the fire retardant doesn’t escape from treated products, indicating that “the risk of exposure … is negligible.”

The Tribune obtained a copy of the study Chemtura cited in the letter. It involved researchers placing saline-soaked filter papers on a cotton-covered block of foam and observing whether Firemaster 550 leached out during the following eight days.

“The study was designed to simulate potential migration from direct skin contact with the foam, and also oral contact, such as a person chewing on the foam,” the company said in a statement.

The study, the company said, “showed no detectable migration from the foam.”

Independent scientists say the Chemtura study was flawed. Other research has found that flame retardants escape from products over periods of time far longer than eight days.

Moreover, Firemaster 550’s brominated chemicals have turned up not only in common household dust but in sewage sludge around San Francisco Bay, polar bears in the Arctic, harbor seals off the coast of Maine, mollusks in North Carolina and porpoises in the South China Sea.

Indiana University researchers reported in November that airborne concentrations are rising in Chicago and other cities around the Great Lakes as well as in more remote areas, such as Michigan’s Upper Peninsula.

So far, little is known about whether Firemaster 550 is building up in people. Early research suggests that its brominated compounds quickly break down into other chemicals in the body, so scientists are studying if they can track those byproducts in blood or breast milk.

“It’s ridiculous that they would keep saying this isn’t migrating from couches and other products,” Stapleton said. “We know this chemical is out there, and we know kids are chronically exposed to it.”

Few health studies

EPA officials acknowledge they know little, if anything, about the safety of not only Firemaster 550 but most of the other 84,000 industrial compounds in commercial use in the U.S.

Unlike Europe, where companies generally are required to prove the safety of their chemicals before use, U.S. law requires manufacturers to submit safety data only if they have it. Most don’t, records show, which forces the EPA to predict whether chemicals will pose health problems by using computer models that the agency admits can fail to identify adverse effects.

The EPA can require studies of new chemicals that it anticipates could affect people’s health — as it did with Firemaster 550 — but this step is rare, and the research doesn’t need to be completed before the chemicals are sold.

To ban a chemical already on the market, the EPA must prove that it poses an “unreasonable risk.” Federal courts have established such a narrow definition of “unreasonable” that the government couldn’t even ban asbestos, a well-documented carcinogen that has killed thousands of people who suffered devastating lung diseases.

When the EPA approved Firemaster 550, the agency knew that it contained two brominated compounds, known as TBB and TBPH. Both are structurally similar to a plastic-softening phthalate that Congress has banned in children’s products. Called DEHP, the phthalate is listed in California as a known carcinogen and developmental toxin.

EPA scientists also have known since the mid-1990s that burning products containing TBB could release highly toxic dioxins, records show.

The only health studies of Firemaster 550 conducted to date are two Chemtura-funded papers that the company submitted in 2008 at the EPA’s request, five years after the agency declared it was safe.

The effects seen in some of the test rats, such as low birth weight and skeletal malformations, often lead to more serious health problems later in life. Yet the industry researchers repeatedly dismissed those effects as “spurious,” “unclear” or “incidental,” saying the problems weren’t seen in all of the animals or when different doses were tested.

The company said its animal tests found no harmful effects at levels “expected to be seen in the environment” and proved that Firemaster 550 is “acceptable for use in the applications for which it was intended.”

Stapleton and Heather Patisaul, a toxicologist at North Carolina State University, now are researching whether low doses of the brominated chemicals in Firemaster 550 could cause harm. Scientists increasingly are finding that the body can mistake tiny amounts of certain chemicals for hormones.

Based on earlier findings about such endocrine disrupters, including penta, Stapleton and Patisaul are looking for signs that Firemaster 550 could mimic or block hormones during critical stages of development.

“This is not a case where we are looking for missing arms and legs,” said Linda Birnbaum, director of the National Institute of Environmental Health Sciences and a veteran government scientist who has raised concerns about toxic chemicals for years. “We’re looking at reduced ability to learn, altered behaviors, decreased sperm count, premature ovarian failure — things that are more difficult to pick up in the standard studies.”

EPA officials said they still think penta is more toxic than Firemaster 550, but they acknowledge missing some of the early warning signs about the newer flame retardant. They blamed the agency’s delayed response on a lack of sufficient staff and funding to assess hundreds of new chemicals introduced by industry every year.

“We are always learning,” said Jones, the EPA’s acting assistant administrator for chemical safety and pollution prevention. “We want to make sure we have a better understanding of the human health and ecological risks before we commit to any course of action.”

‘Why do we not learn?’

Last year, Stapleton was back in her lab testing for flame retardants, this time in baby products.

About a fifth of the nursing pillows, car seats, highchairs, diaper-changing pads and other products made with polyurethane foam contained Firemaster 550, she found. But the most common flame retardant detected was another chemical: chlorinated tris, also known as TDCCP.

Of all the flame retardants used over the years, chlorinated tris is one of the most notorious. Manufacturers voluntarily took it out of children’s pajamas more than three decades ago after it was linked to cancer.

Scientists and regulators thought chlorinated tris had all but disappeared from the marketplace. But because it wasn’t banned, companies could legally use it in other consumer products without informing government officials or the public.

After penta was pulled from the market, chlorinated tris joined Firemaster 550 as the most widely used flame retardants in household furniture.

Chemical companies say chlorinated tris is safe. The American Chemistry Council, the industry’s leading trade group, declined to answer specific questions but emailed a link to its position paper, which states that a 2008 risk assessment by the European Union found “no concerns for consumers in relation to carcinogenicity from potential inhalation or exposure to children via the oral route.”

But several other major health and regulatory agencies have identified the flame retardant as a cancer risk, including the World Health Organization, National Cancer Institute and National Research Council.

In 2006, researchers at the U.S. Consumer Product Safety Commission cautioned that adding chlorinated tris to furniture would expose children to nearly twice the daily dose deemed acceptable by the federal agency. The cancer risk for children during the first two years of life would be seven times higher than what most physicians, scientists and regulators consider acceptable, according to the safety commission’s report.

“Industry has had years to come up with safer alternatives,” said Arlene Blum, a University of California at Berkeley chemist whose 1977 study helped pressure manufacturers to take chlorinated tris out of children’s sleepwear. “They can’t do better than this?”

In a statement, the EPA said it is largely powerless to do anything about chlorinated tris. The agency cited industry’s continued use of the chemical as a stark example of why it supports “much needed reform” of the nation’s chemical safety law.

Jerome Paulson, a George Washington University pediatrician who last year wrote a stinging critique of the law for the American Academy of Pediatrics, said the system especially fails to protect children. The group wants safety standards for industrial chemicals to be more like those governing pharmaceuticals and pesticides, with chemicals being approved only if a “reasonable certainty of no harm” can be verified.

Birnbaum and Ake Bergman, a Swedish researcher who was one of the first to sound alarms about penta building up in mothers and babies, wrote a 2010 editorial in the journal Environmental Health Perspectives that summed up the scientific community’s frustration with the lack of oversight.

“Why do we not learn from the past?” they asked.

With the federal government failing to take action, more than a dozen states are considering legislation that would ban chlorinated tris in children’s products. This spring, Washington state legislators rejected such a ban amid heavy lobbying from the Citizens for Fire Safety Institute, a front group for the world’s largest makers of flame retardants.

Last year, however, California added chlorinated tris to its Proposition 65 list of cancer-causing chemicals.

That means consumers shopping for furniture and baby products might soon be confronted with two labels: one meant to reassure them that the product meets the state’s flammability standards and another to warn them about a chemical linked to cancer.

Aware that new warning labels might scare away customers, Chemtura already is marketing an alternative flame retardant called Emerald NH-1. The company’s website describes the chemical as a member of its “new family of high-performing, greener fire safety solutions.”

The company says the polymer-based substance doesn’t contain bromine or chlorine, the troublesome chemicals in other flame retardants.

But the ingredients remain a trade secret.

Tribune reporter Patricia Callahan contributed.

mhawthorne@tribune.com

http://www.chicagotribune.com/news/watchdog/flames/ct-met-flames-regulators-20120510,0,6880244,full.story

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